4.1.1 Basic Organic Chemistry Flashcards
Definition of hydrocarbon
Compounds that contain ONLY hydrogen and carbon atoms
Stem for C1-10
meth, eth, prop, but, pent, hex, hept, oct, non, dec
Suffix for alkane, alkene, alcohol, carboxylic acid, ketone, aldehyde, ester, amine
-ane, -ene, -ol, -oic acid, -one, -al, - ate, -amine
Name of CH3CH(OH)CH(OH)CH3
butan-2,3-diol
Structural formula of 3-ethyl-5-methylhexan-2-ol
CH3CH(CH3)CH2C(C2H5)CH(OH)CH3
Name of CH3COCH3
propanone
structural formula of 1,2-dichloropropane
CH2ClCHClCH3
Definition of empirical formula
The simplest whole number ratio of atoms of each element in a compound
Definition of homologous series
Series of organic compounds with the same functional group with each member differing by a CH2 group
Definition of alkyl group
Hydrocarbon chain with general formula CnH2n+1
Definition of aliphatic
Compound containing carbon and hydrogen. Can be straight chains, branched chains or non-aromatic rings
Definition of alicyclic
carbon and hydrogen compounds arranged in non-aromatic rings (with or without side chains)
Definition of aromatic
Compound containing a benzene ring
Saturated
Contains single carbon-carbon bonds only
Unsaturated
Contains double or triple carbon-carbon bonds (including aromatic rings)
Isomers
Molecules with the same molecular formula but different arrangement of atoms within the molecule (different structural formula)
Chain isomers
Same molecular formula but different arrangement of the carbon skeleton e.g. straight chains v branched chains
Position isomers
Have the functional group of the molecule in a different position on the carbon chain e.g. propan-1-ol and propan-2-ol
Functional group isomers
Same molecular formula but a different functional group e.g. propanone and propanal
Curly arrow
Movement of a pair of electrons
Homolytic fission
Each bonding atom receives one electron from the bonded pair forming two radicals.
Heterolytic fission
One bonding atom receives both electrons from the bonded pair forming a cation and an anion.
Radical
Species with an unpaired electron
Addition
When two smaller molecules combine to make 1 larger molecule
Substitution
When one functional group is replaced by a different functional group.
Oxidation
Loss of electrons or gain of oxygen or loss of hydrogen
Reduction
Gain of electrons, loss of oxygen or gain of hydrogen
Polymerisation
Reaction where many monomers join to form a large regularly repeating molecule called a polymer
Elimination
A small molecule is removed from a larger molecule