4.10 Using Resources Flashcards

1
Q

Using the Earth’s resources

A

Humans use the Earth’s resources to provide warmth, shelter, food and transport.
Natural resources, supplemented by agriculture, provide food, timber, clothing and fuels.
Examples of natural resources are cotton, crude oil, and timber.
Some resources can be replaced by synthetic products (rubber) and others cannot. natural rubber comes from the sap of a tree, whereas synthetic rubber is made using crude oil (2 thirds of the rubber used in the world is synthetic)

Some natural resources are finite, cannot be replaced as quickly as they are being used. (fossil fuels and metals, huge amounts extracted from the world’s crust) -> we will run out of them one day, limited supply
Example of a renewable resource is wood, we can replace these resources as quickly as we use them -> will never run out

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2
Q

sustainable development

A

Chemistry plays an important role in improving agricultural and industrial processes to provide new products and sustainable development, which is
development that meets the needs of current generations without compromising the ability of future generations to meet their own needs
(we can meet our needs, without preventing future generations meeting their own)

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3
Q

Chemistry’s role, an example of a natural product that has been supplemented/replaced by synthetic products

A

Chemistry plays an important role in how we use our resources. Artificial fertilisers -> allow us to grow more food with the land available, enhances crop yields

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4
Q

importance of water quality for human life and define potable water

A

Water of appropriate quality is essential for life. For humans, drinking water should have sufficiently low levels of dissolved salts (sodium chloride) and microbes (bacteria), pH between 6.5 and 8.5.
Water that is safe to drink is called potable water. Potable water is not pure water in the chemical sense because it contains dissolved substances, whereas pure water just contained H20

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5
Q

methods to produce potable water

A
  • depend on available supplies of water and local conditions

When is rains, water can either collect as surface water (lakes, rivers reservoirs), or as groundwater (in rocks called aquifers that trap water underground)

In the UK, rain provides water with low levels of
dissolved substances (fresh water) that collects in the ground and in lakes and rivers -> good sources of fresh water
  • choosing an appropriate source of fresh water (eg a river)
  • > filtration -water is passed through filter beds to remove materials such as leaves and insoluble particles. Then the water is sterilised to kill microbes, in the UK we use chloride to sterilise potable water. In some parts of the world, other sterilising agents used for potable water are ozone or ultraviolet light
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6
Q

desalination

A
  • however, in many places, fresh water is scarce and the only available water might be too salty -> sea water
    sea water has very high levels of dissolved substances, and potable water is produced by desalination

Desalination reduces levels of dissolved substances to an acceptable level for potable water
Desalination can be done by distillation or by processes that use membranes such as reverse osmosis
- reverse osmosis -> the salty water is passed through a certain membrane that only allows water molecules to pass through, ions and larger molecules are trapped by the membrane -> separated from the water

Both of these processes require large amounts of energy, so they are very expensive, not practical fir producing large amounts of fresh water

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7
Q

RP8: : 1. analysing a sample of water

A
  1. Use pH meter or universal indicator to test the pH of the water. Use an appropriate colour chart and record your observations.
  2. Measure and record the mass of an empty evaporating basin.
  3. Pour 10 cm3 water into the evaporating basin and evaporate the water using a Bunsen burner until no liquid remains
  4. Once the evaporating basin is cool, reweigh and record the change in mass.
  5. Calculate the mass of dissolved solids in the water.
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8
Q

RP8 safety precautions

A

safety goggles must be worn at all times (acidic or alkaline water samples), do not ingest the water -> might be contaminated because the apparatus might not have been cleaned properly before the practical.

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9
Q

RP8: 2. Purifying a sample of water by distillation

A
  1. Place the water sample in a conical flask and set up the apparatus for distillation.
  2. Heat the water gently using a Bunsen burner until it boils. Then reduce the heat so the water boils gently.
  3. Collect around 1 cm depth of water in the cooled test tube, then stop turn the Bunsen burner off.
  4. Analyse the water you have distilled with cobalt chloride paper and determining its boiling point
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10
Q

How could you test to see if the distilled water contained sodium ions and chloride ions?

practical tip for distillation

A

Sodium ions would give a yellow colour in a flame test. Chloride ions would give a white precipitate with silver nitrate solution after a small amount of nitric acid was added.

The delivery tube must sit above the filtrate level to prevent cold water being sucked back up the delivery tube after separation, which would break the hot glass.

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11
Q

waste water treatment

A

Urban lifestyles and industrial processes produce large amounts of waste water that require treatment before being released into the environment. Sewage and agricultural waste water require removal of organic matter (From urine and faeces) and harmful microbes. Industrial (paper and chemicals) waste water may require removal of organic matter and harmful chemicals. Otherwise it would make it very polluted and pose health risks when put back into freshwater sources like rivers and lakes

agricultural systems also produce a lot of waste water, including sludge from animal farms and nutrient run-off from fields

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12
Q

Process of sewage treatment

A
  1. screening and grit removal - by passing through a mesh to remove large particles and grit
  2. sedimentation - sewage is allowed to settle in a settlement tank -> allows tiny particles to settle out from still water -> produces sewage sludge and effluent (the liquid which remains on top)
  3. sewage sludge is digested anaerobically by specific bacteria, releasing methane gas -> used as an energy source, the digested waste can be used as fertilisers
  4. the effluent contains large amounts of organic matter and harmful microbes (need to be reduced before returned to the environment)-> air is pumped into the liquid effluent , allowing aerobic bacteria to multiply. As there’s oxygen, aerobic bacteria digest om and hm
  5. effluent can be safely discharged into rivers or seas
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13
Q

compare the ease of obtaining potable water from waste water as opposed to ground or salt water

A
  • easier and cheaper way to produce potable water is to use groundwater from aquifers
  • sewage treatment to make potable water requires more purification processes (uses less energy than desalination of salty water) -> only done in places where water is scarce
  • desalination requires lots of energy and is expensive -> although seawater is a plentiful raw material -> good for countries with little fresh water
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14
Q

alternative biological methods for extracting metals,

A

The Earth’s resources of metal ores are limited.
Copper ores are becoming scarce and new ways of extracting copper from low-grade ores (only contain small amount of copper -> harder to extract copper economically (cost effective) from these ores) include phytomining, and bioleaching.

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15
Q

phytomining

A

Phytomining uses plants to absorb metal compounds. The plants are grown in areas known to contain metals of interest in the soil. These plants absorb the metal compound and concentrate it in their tissue. The plants are harvested and then burned to produce ash that contains a relatively high concentration of the metal compounds from which the useful metals can be extracted by displacement reactions or electrolysis.

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16
Q

bioleaching

A

Bioleaching uses bacteria to produce leachate solutions that contain metal compounds. Bacteria are mixed with a low grade ore, carrying out chemical reactions and produce an acidic solution called a leachate (contains the metal compound that we want)

The metal compounds can be processed to obtain the metal. For example, copper can be obtained from solutions of copper compounds by displacement using scrap iron (cheaper and more reactive than copper) or by electrolysis
Bioleaching does not need high temperatures, but it produces toxic substances, including sulfuric acid, which damage the environment.

17
Q

displacement reactions

A

reacting a metal with water -> metal hydroxide (alkaline) + hydrogen gas

eg sodium + water -> sodium hydroxide + hydrogen

18
Q

evaluate alternative methods for extracting metals

A

Phytomining and bioleaching are principally used for copper extraction due to the high global demand for copper, but these methods can be applied to other metals.
- phytomining and bioleaching let us economically extract metals from low grade ores -> important as the Earth’s resources of metal ores are limited
These methods avoid traditional mining methods of digging, moving and disposing of large amounts of rock.

19
Q

life cycle assessment

A

If a company wants to manufacture a new product, they carry out a LCA.
Life cycle assessments (LCAs) are carried out to assess the environmental impact of products in each of these stages:
• extracting and processing raw materials
Extracting raw materials can damage the environment -> mining metals. extraction can also result in pollution due to the amount of energy needed
Raw materials often need to be processed to extract the desired materials -> takes lots of energy, eg extracting metals from ores or fractional distillation of crude oil
• manufacturing and packaging
manufacturing products and packaging can use lots of energy and cause lots of pollution- > harmful fumes such as carbon monoxide or hydrogen chloride, some waste can be turned into other useful chemicals, reducing the amount that ends up polluting the environment
• use and operation during its lifetime
the use of a product can damage the environment -> eg fertilisers can leach into streams and rivers, causing damage to ecosystems
how long a product is used for or how many uses is also a factor -> products that need lots of energy to produce but are used for ages -> less waste in the long run
• disposal at the end of its useful life, including transport and distribution at each stage. (chemicals)
using up space at landfill sites pollutes land and water -> paint washes off a product and gets into rivers
energy is used to transport used products to landfill -> causes pollutants to be released into the atmosphere

20
Q

advantages and disadvantages of LCAs

A

Use of water, resources, energy sources and production of some wastes can be fairly easily quantified. Allocating numerical values to pollutant effects is less straightforward and requires value judgements, so LCA is not a purely objective process -> it takes into account the values of the person carrying out the assessment -> LCAs can be biased

Selective LCAs only show some of the environmental impacts of a product which can also be biased, as they can be written to deliberately support the company’s claims -> to give them positive advertising

21
Q

reducing use of resources

A

The reduction in use, reuse and recycling of raw materials by end users reduces the use of limited resources, use of energy sources, waste and environmental impacts.
Metals, glass, building materials, clay ceramics and most plastics are produced from limited raw materials. Much of the energy for the processes comes from limited resources. Obtaining raw materials from the Earth by quarrying and mining causes environmental
impacts. (quarrying produces large amounts of dust and destroys habitats, mining releases harmful chemicals into the environment)

  • Glass bottles reused, and can also be crushed and melted to make different glass products (jars)
  • Other products cannot be reused in this way but can be recycled for a different use -> plastic bottles can be recycled to make fleece jackets and carpets
  • metals are a very useful but limited resource -> Metals can be melted and recast into different products
    one problem is that different metals usually need to be kept separate before being recycled (depends on the properties of the final product)
    Iron for example can be recycled together with waste steel as both materials can be added to a blast furnace, reducing the use of iron ore.
22
Q

advantages and disadvantages of recycling

A

advantages

  • the amount of waste that is disposed of in landfill is reduced
  • fewer quarries and mines are needed to extract finite reserves of metal ores
  • less energy is needed for recycling compared with making a new product from natural resources, so the emission of greenhouse gases is reduced

disadvantages

  • the collection and transport of used items needs organisation, workers, vehicles and fuel
  • it can be difficult to sort different metals from one another
23
Q

corrosion and its prevention

A

Corrosion is the destruction of materials by chemical reactions with substances in the environment
Rusting is an example of corrosion. Rusting only applies to iron and to alloys of iron such as steel. Both oxygen (air) and water are necessary for iron to rust.

iron + oxygen + water -> hydrated iron (III) oxide

Corrosion can be prevented by applying a coating that acts as a barrier (blocking oxygen), such as greasing, painting or electroplating. Aluminium has an oxide coating that protects the metal underneath from further corrosion. Some coatings are reactive and contain a more reactive metal (zinc or magnesium) to provide sacrificial protection
▪ E.g. zinc is used to galvanise iron (galvanising is coating a metal with zinc)
layer of zinc acts as a barrier against air and water -> prevents iron from corroding. even if the zinc gets scratched, it still prevents corrosion as zinc is more reactive than iron (loses its electrons more readily)-> tthe water and oxygen react with the sacrificial metal rather than the iron

24
Q

alloys as useful materials

A

Alloys are mixtures of metals where the metals are not chemically combined. This disrupts the structure of the metal, making alloys harder than pure metals (for every day use)
eg. alloys of iron called steels are often used instead of pure iron -> Steels are alloys of iron that contain specific amounts of carbon and other metals. High carbon steel is strong but brittle.(cutting tools) Low carbon steel is softer and more easily shaped (used for sheeting, malleable) Steels containing chromium and nickel (stainless steels) are hard and resistant to corrosion. (cutlery)

  • Bronze is an alloy of copper and tin - bronze is harder than copper and is used to make medals, decorative ornaments and statues
  • Brass is an alloy of copper and zinc - brass is more malleable than bronze, used where lower friction is needed -> water taps and door fittings
  • Gold used as jewellery is usually an alloy with silver, copper and zinc. Pure gold is very soft. The proportion of gold in the alloy is measured in carats. 24 carat being 100% (pure gold), and 18 carat being 75% gold.
  • aluminium alloys - has a low density, important factor needed in aircraft manufacture
    pure aluminium is too soft for making aeroplanes; alloyed with small amounts of other materials to make it stronger
25
Q

ceramics

A

ceramics are non metal solids with high melting points that aren’t made from carbon based compounds. Due to their high melting points and resistance to stains, ceramics are used in kitchen and dinnerware. -> insulators of heat and electricity, brittle and stiff

-some ceramics can be made from clay
soft material when it’s dug up out of the ground, can be moulded into different shapes. It hardens to form a clay ceramic after heating in a furnace -> ability to be moulded when wet means clay is ideal for pottery and bricks

  • glass -generally transparent, can be moulded when hot, brittle when thin
    Most of the glass we use is soda-lime glass, made by heating a mixture of sand, sodium carbonate and limestone. (windows and bottles)
  • > low melting point, limits its uses
    Borosilicate glass, made from sand and boron trioxide, melts at higher temperatures than soda-lime glass.
    -> higher melting point means useful for objects that require heating, kitchenware and labware
26
Q

composites

A

Most composites are made of two materials, a matrix or binder surrounding and binding together fibres or fragments of the other material, which is called the reinforcement. The properties of a composite depend on the properties of the material it’s made from

  1. fibreglass - reinforcement - glass fibres, matrix - polymer resin. low density like plastic but very strong like glass, used for skis, boats and surfboards
  2. carbon fibre- reinforcement - long chains of carbon atoms bonded together (carbon fibres) or from carbon nanotubes. matrix - polymer
    very strong and light -> used in aerospace and sports car manufacturing
  3. reinforced concrete - reinforcement - aggregate (mixture of sand and gravel) / steel , matrix - cement
    very strong, ideal building material - in skate parks
    4.wood - natural composite of cellulose fibres held together by an organic polymer matrix
27
Q

polymers

A

A polymer is formed by joining together a large number of monomers (small identical molecules)
The properties of polymers depend on what monomers they are made from and the conditions under which they are made.

insulators of heat and electricity, flexible and easily moulded, used in clothing and insulators in electrical items, grocery bags

28
Q

polymers - explain how low density and high density poly(ethene) are both produced from ethene

A

Low density polyethene and high density polyethene, are both made under different reaction conditions using different catalysts.

  • LD poly(ethene) is made from ethene at a moderate temperature under high pressure with a catalyst -> flexible and soft, used for bags and bottles
  • HD poly(ethene) is also made from ethene but at a lower temperature and pressure from a different catalyst
  • > more rigid, used for water tanks and drainpipes

to change the properties of a polymer - change the reaction temperature, the reaction pressure or the catalyst

29
Q

polymers - explain the difference between thermosoftening and
thermosetting polymers in terms of their structures.

A

Thermosoftening polymers melt when they are heated.
-> can reshape when they are soft and then go back to a solid when we cool them back down

in thermosoftening polymers, the the polymer chains are held to each other by intermolecular forces, which break if we heat the polymer. Now the polymer strands can separate from each other and the polymer melt. If we cool the polymer, we reform the intermolecular forces and the polymer goes back to a solid
There are weak intermolecular forces between the chains, easy to separate

Thermosetting polymers do not melt when they are heated
-> polymer chains are connected to eachother by strong crosslinks and are not broken by heat

30
Q

brittle

A

aren’t very flexible and break easily

31
Q

metals

A

metals are malleable, good conductors of heat and electricity, shiny and stiff
electrical wires, cutlery and car body work