4.1 Basic concepts and hydrocarbons Flashcards

1
Q

Define ‘homologous series’

A

a series of organic compounds having the same functional group but with each successive member differing by CH2

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2
Q

What is an aliphatic hydrocarbon?

A

a hydrocarbon with carbon bonds joined in a straight or branched chain

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3
Q

What is an alicyclic hydrocarbon?

A

a hydrocarbon with carbon atoms joined in a ring structure

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4
Q

What is an aromatic hydrocarbon?

A

a compound containing at least 1 benzene ring

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5
Q

What is the general formula for alkyl groups?

A

Cn H(2n+1)

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6
Q

What is the general formula for alkanes?

A

Cn H(2n+2)

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7
Q

Define ‘functional group’

A

a group of atoms responsible for the characteristic reactions of a compound

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8
Q

Define ‘saturated’ and ‘unsaturated’ hydrocarbons?

A

saturated - single c-c bonds
unsaturated - double c=c bonds or more

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9
Q

What is the general formula?

A

the simplest algebraic formula of a member of a homologous series

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10
Q

What is the structural formula?

A

the minimal detail that shows the arranhement of atoms in a molecule
e.g. propane - CH3CH2CH3

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11
Q

What is the displayed formula?

A

the relative positioning of atoms and the bonds between them
e.g. ethanol
H H
H - C - C - O - H
H H

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12
Q

What is the skeletal formula?

A

simplified organic formula
e.g ethane = ___

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13
Q

Define ‘structural isomers’

A

compounds with the same molecular formula but different structural formulae

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14
Q

Define ‘homolytic fission’

A

each bonding atom receives 1 electron from the bonded pair - forming 2 radicals

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15
Q

Define ‘heterolytic fission’

A

1 bonding atom receives both electrons from the bonding pair

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16
Q

Define ‘radical’

A

a species with an unpaired electron

17
Q

What is a curly arrow?

A

shows the movement of an electron pair - showing either heterolytic fission or formation of a covalent bond

18
Q

What are the properties of alkanes

A

saturated hydrocarbons containing single C-C and C-H bonds as sigma bonds - overlap of orbitals between binding atoms
-giving free rotation of sigma bond

19
Q

Why do alkanes have a tetrahedral shape and bond angle 104.5 ?

A
20
Q

Explain the trends in boiling points of alkanes with different carbon chain lengths and branching

A