4.1-Atomic Structure and the periodic table Flashcards

1
Q

What is an atom?

A

An atom is the smallest part of an element that can exist.

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2
Q

What is an element?

A

An element is a substance that is made of only one type of atom. Elements can exist as single atoms, molecules or giant structures.

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3
Q

Where are the elements found?

A

Each element can be found on the periodic table, and there are about 100 atoms. Each one can be represented by its own symbol and has its own individual name.

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4
Q

What is a compound?

A

A compound contains two or more elements chemically combined in fixed proportions. Compounds can only be separated through a chemical reaction.

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5
Q

How do you name elements?

A

find the symbol on the periodic table, and use its name

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6
Q

How do you name compounds with a metal and a non-metal?

A

never change the name of the metal (always written first) The non metals ending changes to ide.

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7
Q

How do you name compounds with two non-metals?

A

name of the first element stays the same, and the ending of the second element changes to ide. If there are two of the second element, then add a di in front (eg. carbon dioxide)

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8
Q

How do you name a compound with a metal and two non-metals (where one is oxygen)

A

ending of the non-metal (that is not oxygen) changes to ate.

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9
Q

What do chemical reactions show?

A

Chemical equations show the reactants (the substances you start with) and products (the substances made) in a reaction.

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10
Q

How can you represent chemical reactions?

A

You can represent reactions as word equations or symbol equations.

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11
Q

What happens in a chemical reaction?

A

In chemical reactions, the atoms get rearranged and are bonded together.

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12
Q

What do balanced symbol equations help you to see?

A

Using symbol equations helps you see how much of each substance is involved in a reaction.
If an equation is balanced, there is the same number of each type of atom on both sides of the equation.
This is important, because atoms cannot be created or destroyed in a chemical reaction.

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13
Q

What is the law of conservation of mass?

A

The total mass of the products formed in a reaction is equal to the total mass of the reactants.

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14
Q

What are the state symbols?

A

(s)-solids
(l)-liquids
(g)-gases
(aq)- aqueous solutions- substances that are dissolved in water

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15
Q

What is a mixture?

A

A mixture consists of two or more elements or compounds not chemically combined together. The properties of each substance in the mixture are unchanged.

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16
Q

What are the differences between compounds and mixtures?

A

-Compounds have a fixed proportion, but mixtures do not
-Mixtures can be separated using physical separation, whereas compounds are separated using chemical separation
-There are chemical bonds in a compounds, but there aren’t in a mixture

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17
Q

What is filtration used to separate?

A

Filtration is used to separate an insoluble solid from a liquid.

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18
Q

Method for filtration?

A

First, the apparatus must be set up with the filter paper sitting in the filter funnel above a flask or beaker. Then, the mixture needing to be separated must be poured into the filter paper

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19
Q

Why does filtration work?

A

The liquid particles are small enough to pass through the filter paper, but the solid particles are too large to fit through the filter paper and so are left behind. The solid left behind is called the residue, and the liquid in the beaker is called the filtrate.

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20
Q

What is crystalisation used to separate?

A

Crystallization is used to separate a soluble solid from a liquid.

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21
Q

Method for crystalisation?

A

A solution is placed in an evaporating basin and heated with a bunsen burner. As the solution is heated, the water in the solution evaporates and this means that the amount of water in the solution will decrease as it turns into a gas and escapes into the air. As this happens, the solid particles which were dissolved in the water are left behind. Once all of the water has evaporated, the solid is left behind on the bottom and sides of the evaporating basin.

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22
Q

What is simple distillation used for?

A

Simple distillation is used to separate a liquid solvent from a dissolved solid.

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23
Q

Method for simple distillation?

A

Set up the apparatus so that the solution in the flask is fitted with a condenser so that any of the gases produced travel through the condenser. The solution is then heated with a bunsen burner. As the water heats up, it evaporates and its vapors rise and pass through the condenser. The condenser is surrounded with cold water and so the water vapor molecules cool down and turn back into a liquid as they travel through the condenser. Liquid water droplets are collected in the beaker at the end. Once all of the water has been collected, the salt that was dissolved in the solution will also be left behind in the flask.

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24
Q

What is fractional distillation used for?

A

Fractional distillation is used to separate two or more liquids that have different boiling points.

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25
Method for fractional distillation?
Step 1:- In this step, mixture is heated, and after heating, it is passed into the fractionating column. Step 2:- The mixture gets converted into vapours, and the various components of the mixture are evaporated at different temperatures. Step 3:- These vapours rise through the column and get condensed as it cools down and the temperature drops. Step 4:- The liquid with the lower melting point is collected at the top and the liquid with the higher melting point is collected at the bottom. The boiling point of separated fractions in the fractionating column increases from top to bottom.
26
What is chromatography used for?
Chromatography is used to separate two or more dissolved solids from a solution.
27
Method for chromatography?
1. Draw a horizontal pencil line 2 cm from the short edge of the chromatography paper. Mark pencil spots at equal intervals across the line but not too close to the end of the paper. 2. Use a glass capillary tube to put a small spot of each colouring on the pencil spots. A small spot ensures that the colouring separates clearly. Label each spot in pencil. 3. Pour about 1 cm³ of water into the beaker. 4. Suspend the paper in the beaker so that bottom edge of the paper dips into the water. 5. Wait for the water solvent to travel at least three quarters of the way up the paper. Remove the paper and draw another pencil line at on the dry part of the paper right next to the wet edge. This is the solvent front, the distance travelled by the solvent. 6. Hang the paper up to dry thoroughly. 7. Calculate the Rf values for each spot. Rf value is calculated by distance travelled by substance / solvent front.
28
What will a pure substance look like on the chromatogram?
A pure substance will only have one spot on the chromatogram, whereas a mixture would produce more than one
29
What is the retention factor (Rf value)
a measure of the position of a component in a chromatographic separation.
30
How do you calculate Rf value?
distance moved by substance / distance moved by solvent
31
What was Rutherford's experiment?
Later on, a scientist named Rutherford did an experiment called the scattering experiment. He aimed a beam of alpha particles at a thin layer of gold foil, which was only a few atoms thick. They expected the alpha particles to travel through the thin foil without being deflected, if the plum pudding model was correct.
32
What is the Plum Pudding model?
The atom was thought to consist of negatively charged electrons (the ‘plums’) in a positively charged ‘dough’ or ‘pudding’ Since electrons have a negative charge, it was reasoned that the rest of the atom would be positive, making the atom neutral overall.
33
What was Rutherford's actual results?
most of the alpha particles travelled through the foil as expected, but a few other particles were deflected in lots of different directions. Some were even deflected back to where they had come from
34
What did Rutherford's results show?
the positive charge was not spread throughout the atom, but instead concentrated in a small area at the centre of each atom. This area was called the nucleus
35
What did Bohr suggest?
He suggested that instead of all the electrons rotating around the nucleus in the same areas, the electrons rotated around the nucleus in fixed energy levels, called shells. He also suggested that the electrons orbited at specific distances away from the nucleus.
36
What did Chadwick discover?
neutrons
37
What is the charge and mass of an electron?
Charge = -1, Mass = negligible
38
What is the charge and mass of a proton?
Charge = +1, Mass = 1
39
What is the charge and mass of a neutron?
Charge = 0, Mass = 1
40
What is the overall charge of an atom?
the number of electrons is equal to the number of protons in the nucleus. Atoms have no overall electrical charge.
41
What is an element's atomic number?
The number of protons in an atom of an element is its atomic number. All atoms of a particular element have the same number of protons. Atoms of different elements have different numbers of protons.
42
What is an ion?
An ion is a charged particle. If an atom loses electrons, it becomes a positive ion and if it gains electrons, then it becomes a negative ion. For example, when an oxygen atom loses 2 electrons, it becomes an O2+ ion.
43
What is the size of the atomic radius of an atom?
The atomic radius of the atom (the distance from the center of the atom to the outer edge of the atom) is 0.1 nanometres. This is around 1 x 10-10 m.
44
What is the size of the nucleus of an atom?
The nucleus of an atom is 1/10000 the size of an atom. This is about 1 x 10-14 m.
45
What is the mass number of an atom?
The sum of the protons and neutrons in an element is its mass number.
46
What is an isotope?
Atoms of the same element can have different numbers of neutrons; these atoms are called isotopes of that element.
47
What is the relative atomic mass?
Relative atomic mass is the weighted mean mass of an element, taking into account all of the different isotopes and their relative abundance.
48
How do you calculate relative atomic mass?
Relative atomic mass = (mass of the isotope x % abundance) / 100 When you have more than one isotope, the isotopes are multiplied by their corresponding % abundance and then added together and divided by 100.
49
How many electrons can go in each shell?
First shell = 2 electrons Second shell = 8 electrons Third shell = 8 electrons The electronic structure of an atom is written as (number of electrons in first shell, in second shell, in third shell etc.)
50
What does the chemical properties of an element depend on?
The chemical properties of an element depend on how many electrons it has. The way an element reacts is determined by the number of electrons in its outermost shell. Since all the elements in one group have the same number of electrons in their outermost shell, they all react in a similar manner.
51
How are the chemical elements arranged in the periodic table?
The chemical elements are placed in order of their atomic number in the periodic table. This arranges the elements so that they line up in groups (columns) with similar properties. There are 8 main groups in the periodic table. The periodic table also gives a summary of the electronic structures of all the elements. Elements in the same group of the periodic table react in similar ways, since they have the same number of electrons in their outermost shell.
52
Why is the periodic table called the periodic table?
The periodic table is called the periodic table because of the regularly repeating patterns in the properties of elements.
53
How did John Dalton arrange the periodic table?
Arranged elements in order of atomic weights. Published a list of elements in A New System of Chemical Philosophy.
54
How did John Newlands arrange the periodic table?
Ordered known elements by atomic mass. Identified a repeating pattern where every eighth element had similar properties. Assumed all elements had been discovered, leading to inconsistencies. The pattern only worked up to calcium, then broke down. His ideas were ridiculed because elements with different properties were grouped together.
55
How did Mendeleev arrange the periodic table?
Russian chemist Dmitri Mendeleev arranged 50 known elements in order of atomic weights. He arranged them so that a regularly occurring pattern in their properties could be seen Left gaps for undiscovered elements and predicted their properties. (eg. gallium) When new elements were discovered, their properties closely matched his predictions. His table was a major breakthrough in understanding elements.
56
What did the discovery of isotopes mean in relation to the periodic table?
Later, the discovery of isotopes explained why ordering strictly by atomic weight was sometimes incorrect. The modern periodic table arranges elements by atomic number, resolving inconsistencies in Mendeleev’s table
57
How is the modern periodic table arranged?
Elements are arranged in order of atomic number (proton number), not atomic mass. Groups contain elements with similar chemical properties. Mendeleev’s table provided the foundation for the modern periodic table.
58
What are metals and non-metals?
Elements that react to form positive ions are metals, whereas elements that react to form negative ions are non-metals.
59
What are the differences between metals and non-metals?
Metals are generally conductors, whereas non-metals are generally insulators Metals generally have much higher melting and boiling points Non-metals are brittle, whereas metals are malleable and ductile
60
What are noble gases?
elements in Group 0 of the periodic table
61
How reactive are noble gases?
They are unreactive and do not easily form molecules because their atoms have stable arrangements of electrons.
62
How many electrons are in the outershell of a noble gas?
The noble gases have eight electrons in their outer shell, except for helium, which has only two electrons.
63
What are the boiling points of noble gases?
The boiling points of noble gases are quite low, and there is a trend going down the group. The boiling points of the noble gases increase with increasing relative atomic mass (going down the group).