4. Superconductivity Flashcards
What is superconductivity?
A phenomenon whereby certain pure metals, alloys and compounds the resistance to current flow sharply decreases to zero at a particular temperature.
What 2 properties define superconductors
The combination of perfect conduction and perfect magnetic field expulsion is what defines a superconductor.
What is the critical temperature Tc?
The temperature at which the transition to superconductivity occurs is known as the critical temperature, Tc.
How is the magnetic field expelled from the centre of a superconducting sample?
Consider a solid sphere of superconducting material. If a magnetic field is then applied, currents are induced in the surface of the sphere, which exactly oppose the applied field and cause no magnetic field to penetrate the sample.
What is the Meissner effect?
the expulsion of magnetic flux when a material becomes superconducting in a magnetic field.
Describe the mechanism behind cooper pair formation
- As an electron moves through the positively charged ion cores of the lattice it attracts them and causes a distortion
- The distortion of the lattice causes the local area to gain a small net positive charge
- The area of positive charge can attract another electron towards the first
- This attraction can overcome the repulsive forces between the lectron and create a bindng between the two electrons
- The electrons can then travel through the lattice as a single entity, known as a Cooper Pair
What is the coherence length?
The mean separation at which pair correlation becomes effective, or the mean separation between conduction electrons in a Cooper Pair in a metal. (Cooper pairs overlap greatly. In between one pair, there may be up to 107 other electrons which are themselves bound as pairs)
What stops Cooper pairs from exchanging energy with the lattice?
The fact that all cooper pairs are in the same quantum state (are coherent) prevents a single pair from interacting with the lattice and exchanging momentum. For there to be any exchange with the lattice the cooper pair must be broken, this requires a certain amount of energy: the binding energy of the cooper pair. (this is why temp has to be low, otherwise cooper pairs would be broken)
What principle do particles with half integer spins follow
Pauli exclusion principle, each energy level can only contain 2 particles of opposite spin
What principle do particles with integer spins follow?
they dont obey the pauli exclusion principle, and thus any number of particles can occupy the same energy level
What condition must be met for conduction to stop in a superconductor?
In order to stop the current, however, all of the pairs must be broken which would require a considerable combined effort. At the transition temperature, there are no more cooper pairs left
What are two limitations on superconductivity except for a maximum temperature?
Superconductivity is destroyed by the application of a sufficiently large magnetic field (The critical magnetic field depends on how far below the critical temperature the material is) or if the flowing electrical current density exceeds a critical value.
What is the difference between type I and type II superconductors
They differ in regard to their magnetic properties: type I have a sharp transition from the superconducting state where all magnetic flux is expelled to the normal state, where as type II exhibit similar behaviour by completely excluding a magnetic field below a lower critical field value and becoming normal again at an upper critical field. However, when the magnetic field is between these lower and upper critical fields, the superconductor enters a “mixed state” where there is partial penetration of flux.
Describe the magnetic flux behaviour of type II superconductors in their ‘mixed state’
In order to lower the overall magnetic energy, the material allows bundles of flux to penetrate the sample. Within these filaments, the magnetic field is high and the superconductor reverts to normal conducting behaviour. Around each of the filaments is a circulating vortex of screening current which opposes the field inside the core. This arrangement ensures that the material outside these bundles remains in the superconducting state.
How do the flux vortices arrange themselves in type 2 semiconductors’ mixed state?
The flux vortices often arrange themselves into regular periodic structures. They can be visualised by covering the surface with a coagulation of very fine ferromagnetic particles.