4 - Ionic Equilibrium Flashcards

0
Q

Explain ionization/dissociation

A

When molecules are dissolved in water and break up into ions which can freely move throughout the solution

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1
Q

What is an ion

A

A small particle that is electrically charged

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2
Q

What is an electrolyte

A

Because ions are electrically charged they can transport electrical charge when they are in solution. When they do this they are known as electrolytes

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3
Q

Define an acid and a base

A

Acid - a substance which increases the H+ (H3O+) concentration when dissolved in water
Base - a substance the increases the OH- concentration when dissolved in water

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4
Q

What is the difference between strong and weak acids/bases

A

A strong acid/base is one that completely dissociates, while a weak acid/base is one that only partially dissociate

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5
Q

Define monoprotic and polyprotic acids

A

The molecules of a monoprotic acid contains only one proton and dissociate in one step
The molecules of a polyprotic acid contain more than one proton and dissociate in multiple steps

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6
Q

What is the equation for degree of dissociation

A

Degree of dissociation (a) = (dissociates electrolyte at eq)/(total electrolyte)

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7
Q

What is autoionization

A

Proton transfer between two molecules of the same substance (eg.water)

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8
Q

Define the concept of pH

A

The degree to which a solution in water is acidic or basic. The pH value actually only refers to the proton concentration

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9
Q

What does a buffer consist of

A

A weak acid and a weak base

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10
Q

What is hydrolysis

A

The reaction of an ion with water

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11
Q

What is solubility

A

Solubility is the degree to which a material (solute) will dissolve in another material (solvent)

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12
Q

What is precipitation

A

The process of dissolved anions and cations combining to form a solid salt

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13
Q

What is the solubility product constant

A

The product of the concentrations of the dissociated ions involved

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14
Q

Explain what is meant by saturation and supersaturation

A

Saturation - a point of equilibrium between dissociation and precipitation
Supersaturation - when a solution contains more dissolved salt than the solubility of the salt actually allows

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15
Q

What is the ion product

A

The product of ions in the solution

16
Q

What is the common ion effect

A

When a salt is dissolved it dissociates into two ions. If one of these ions is already present in the water we use as a solvent, the salt will be less soluble than we would expect

17
Q

What are complex ions

A

Two or molecules (ligand) bonded to a metal cation via dative covalent bonding