4. Equations Flashcards
Combustion vs combination rxns vs decomposition rxns vs single replacement vs double replacement vs neutralization rxns
hydrocarbon + oxidant (usually O2) -> CO2 + H2O vs A + B -> C vs C -> A + B vs A + BC -> B + AC vs AB + CD -> AD + CB vs subset of double replacement, acid + base -> salt + H2O
Steps to balance eqns
Metals/nonmetals, H, O
You balance eqns to reflect laws of mass conservation and charge
Know how to find limiting reagent and excess reagent
Convert g to mol, stoich mol of reactant and product; smaller mol value = LR, find difference b/w small and big mol values and change from mol to g
Eqn for percent yield. Steps to find it
(actual/theoretical) x 100
1) Balance eqn, 2) use complete stoich to find starting grams given to find target grams, 3) percent yield eqn
Is going right or going up more impt for stronger electronegativity?
Right > up
[O] #’s for elemental states vs mono atomic ions
0 vs their charge
Gram equivalent weight
Molar mass/n
n = # of target particles produced or consumed in a rxn (ex: you need 31 g of H2CO3 (molar mass=62 g) to make 1 equivalent of H ions cuz each H2CO3 gives 2 H ions
Normality (N)
Measure of conc expressed in equivalents/L; usually done for [H+]. Ex: 1 N HCl = 1 M HCl cuz there’s 1 H ion, 1 N H2CO3 = 0.5 M H2CO3 cuz there’s 2 H ions
molarity = normality/n where n=# of p+, e-, or ions produced or consumed by solute
Law of constant composition. How to find percent composition
Any pure sample of cmpd will have identical mass ratio
(Mass of element in formula/molar mass) * 100
Electrolytes and examples
Solutes that allow slns to carry currents. Strong ex: ionic cmpds like NaCl and KI; highly polar covalent bonds that dissociate when dissolved like HCl; ionic cmpds that can dissolve into greatest amount of cat/anions. Weak ex: molec that ionizes or hydrolyzes weakly in water like acetic acid (basically weak acids) and NH3 (basically weak bases)
Electrolytes prevent charge buildup and inc conductivity in electrolysis; electrolytes should not be [O] or [H]
Molecular weight vs formula weight
Sum of masses of all atoms within molec vs sum of masses of all atoms within ionic cmpds (usually from empiric formula)
How to find empirical formula?
1) imagine percentages in 100 g sample
2) divide percentages by molar mass of element
3) divide the resulting ratio by smaller revalue
4) those answers acts subscripts for empirical formula