3a) Elements, Water And Organic Chemistry Flashcards

0
Q

How did Newlands organise his elements?

A

They were arranged in octaves (8s)

Every 8th had similar properties

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1
Q

In the 1800s how could elements be classified?

A

By physical properties
Chemical properties
Relative atomic mass

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2
Q

Why did Newlands method not work?

Why did the scientific community not like it?

A

He didn’t leave gaps for undescovered elements
His groups had elements without similar properties
He mixed up metals and non metals

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3
Q

How was Dmitri Mendeleev’s periodic table organised?

A

In order of atomic mass
He left gaps for undescovered elements so could predict their properties
Elements with similar properties were put in groups (vertical columns)

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4
Q

Describe the modern periodic table.

A

Arranged by electronic structure - you can predict their chemical properties
Shells hold electrons
Groups have the same no. of electrons in their outer shell
The more shells the less attraction

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5
Q

Describe the changes as you go down group 1 (alkali metals)

A

Elements become more reactive (outer electron more easily lost - further from the nucleus)
Lower melting and boiling points

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6
Q

What type of compounds are made when group one and seven bond?
Why does this happen?

A

Ionic compounds
Lose their one outer shell electron to form a 1+ ion.
Produce white compound which dissolve in water to form colourless solutions

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7
Q

What happens as you go down group seven (halogens)?

A

Less reactive - harder to gain an electron - further from the nucleus
Higher melting and boiling points

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8
Q

Name the coloured vapours that halogens form

A

Fluorine: very reactive, yellow gas
Chlorine: fairly reactive, dense green gas
Bromine: red brown volatile liquid
Iodine: dark grey crystalline solid or purple vapour

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9
Q

Describe the properties of transition elements

A

Good conductors
Dense, strong, shiny
Less reactive don’t react as vigorously as group 1
Higher melting points

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10
Q

List the coloured compounds of transition metals

A

Potassium chromate VI: yellow
Potassium manganate VII: purple
Copper II sulphate: blue

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11
Q

List the use of transition metals as catalysts

A

Iron: haver process - ammonia
Manganese IV oxide: decomposition of hydrogen peroxide
Nickel: oils into fats - margarine

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12
Q

Describe the properties of hard water

A

Build up of scum - dissolved Ca ions and Mg ions react with soap
When heated creates scale (which reduced the efficiency off appliances)

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13
Q

Advantages of hard water

A

Ca2+ is good for bones and teeth

People who live with it are “less likely to develop heart disease”

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14
Q

How is temporary hardness removed?

A

By boiling. The Ca HCO3 decomposes to form CaCO3

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15
Q

How can temporary and permanent hardness be removed?

A

By adding sodium carbonate. It forms an insoluble precipitate, so can’t be dissolved in water to make it hard

Also by ion exchange columns which replace Ca and Mg for Na and H

16
Q

How is water from reservoirs treated?

A

1) water passes through a mesh screen
2) chemicals are added to make solids and microbes stick
3) water is filtered through gravel to remove solids
4) water is chlorinated to kill microbes

17
Q

Advantages and Disadvantages of adding Fl and Cl to water

A

Ad:
Fl reduces tooth decay
Cl prevents disease

Disad:
Cl, increases certain cancers - reacts with natural things to get toxic byproducts
Fl causes cancer in high doses and bone problems - shouldn’t be added
Levels of chemicals need to be monitored

18
Q

Define a reversible reaction

A

Where the products of the reaction can themselves react to produce the original reactants

19
Q

The haber process: why is pressure high and temperature low?

A

To give the best %yeild without too much expense. As the forward reaction is preferred
Increasing the temp changes the equilibrium so yeild is greater at lower temps
Lower temps mean a lower rate of reaction.
The 450°c is a compromise between max yeild and speed of reaction
Ammonia forms as a gas, cools, condenses, liquifies and is removed
Unused H and N re-cycled

20
Q

What is the generic formula of an alcohol?

A

CnH2n+1OH

21
Q

Why are alcohols used as solvents?

Fuels?

A

It can dissolve substances that water can’t.
Clean burning - less pollution
Grown from sugar cane - renewable

22
Q

Functional group of carboxylic acids

A

COOH

23
Q

Word equation for reaction of carboxylic acids with carbonates

A

Ethanoic acid + sodium carbonate –> carbon dioxide + sodium ethanoate

24
Q

Word equation of oxidation of ethanol

A

Ethanol + oxygen –> ethanoic acid + water

25
Q

Functional group of esters

A

COO

26
Q

Properties of esters

A

Pleasant smell
Volatile
Flammable
Don’t mix with water

27
Q

Functional group of Alcohol

A

-OH

28
Q

Where are esters used?

A

Perfumes
Flavouring and aromas
Ointments
Solvents

29
Q

Problems with using esters

A

Inhaling fumes irritates mucous membranes
Very flammable - cause flash fires
Toxic - health problems