3.5 Lipids Flashcards

Chapter 3 - Biological Molecules

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1
Q

What are lipids?

A

Non-polar macromolecules containing the elements carbon, hydrogen and oxygen. Commonly known as fats and oils.

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2
Q

Why are lipids not soluble?

A

There are no positive and negative areas within the lipid molecules as they are non-polar. This means that the electrons in the outer orbitals that form the bonds are more evenly distributed than in polar lipid molecules.

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3
Q

What are macromolecules?

A

Large complex molecules with a large molecular weight.

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4
Q

What is a triglyceride?

A

A lipid composed of one glycerol molecule and three fatty acids.

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5
Q

What elements make up a triglyceride molecule?

A
  • Carbon (C)
  • Hydrogen (H)
  • Oxygen (O)
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6
Q

What is glycerol?

A

An alcohol found in triglycerides.

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7
Q

What are fatty acids?

A

Long chains of carboxylic acids used in the formation of triglycerides.

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8
Q

What functional group is found in both glycerol and fatty acids?

A

Hydroxyl group (OH)

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9
Q

How are triglycerides formed?

A

Hydroxyl groups interact on the glycerol molecule and fatty acids producing three water molecules.

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10
Q

What type of bonds form between a glycerol molecule and three fatty acids? and what type of reaction is this?

A

Ester bonds formed in an esterification reaction, a type of condensation reaction.

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11
Q

Why are triglycerides also an example of a hydrolysis reaction?

A

Three water molecules are needed to be supplied to break down the triglyceride molecule into one glycerol molecule and three fatty acids.

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12
Q

What are saturated triglycerides?

A

Fatty acid chains that have no double bonds present between the carbon atoms .

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13
Q

What are unsaturated tryiglycerides?

A

Fatty acid chains that have double bonds present between the carbon atoms.

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14
Q

What is meant by a monosaturated triglyceride?

A

If the fatty acid chain contains one double bond between its carbon atoms.

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15
Q

What is meant by a polyunsaturated triglyceride?

A

If the fatty acid chain contains two or more double bonds between its carbon atoms.

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16
Q

Why are saturated triglycerides described as oils rather than fats?

A

The presence of double bonds causes the molecule to kink or bend and they therefore cannot pack so closely together. This makes them a liquid at room temperature rather than a solid.

17
Q

What are phosopholipids?

A

Modified triglycerides, where one fatty acid has been replaced with a phosphate group.

18
Q

What elements make up a phospholipid molecule?

A
  • Carbon (C)
  • Hydrogen (H)
  • Oxygen (O)
  • Phosphorus (P)
19
Q

Why are the inorganic phosphate ions soluble in water?

A

Phosphate ions have extra electrons and so are negatively charged.

20
Q

What is meant by being hydrophobic?

A

The physical property of a molecule that is repelled by water.

21
Q

What is meant by being hydrophilic?

A

The physical property of a molecule that is attracted to water.

22
Q

Which areas of phospholipids are hydrophobic and hydrophilic?

A

Non-polar ends (fatty acid chains) is hydrophobic and the charged head (phosphate ion) is hydrophilic.

23
Q

Why are phospholipids called surface active agents or surfactants?

A

They form a layer on the surface of the water with the phosphate heads in the water and the fatty acid tails sticking out of the water. (like oil bubbles in water)

24
Q

Why do phospholipids play a key role in the formation of cell membranes?

A

They are able to separate the external aqueous environment from the aqueous cytosol within cells.

25
Q

What are sterols?

A

Another type of lipid found in cells, also know as steroid alcohols.

26
Q

What is the structure of sterols?

A

Four carbon ring structure with a hydroxyl (OH) group at one end.

27
Q

What areas of sterols are hydrophobic and hydrophilic?

A

The hydroxyl (OH) group is polar and therefore hydrophilic and the rest of the molecule is hydrophobic.

28
Q

What are cholesterols?

A

A sterol.

29
Q

Where does the body manufacture cholesterols?

A

Liver and Intestines.

30
Q

Why are cholesterols important in the formation of cell membranes?

A

They are positioned between phospholipids with their hydroxyl (OH) at the periphery of the membrane. This adds stability to the cell membranes and regulates fluidity but keeping membranes fluid at low temperatures and stopping them from becoming too fluid at high temperatures.

31
Q

Give some examples of molecules manufactured by using cholesterols?

A
  • Vitamin D
  • Steroid hormones
  • Bile
32
Q

What are some biological roles of lipids?

A
  • Membrane formation and the creation of hydrophobic barriers.
  • Hormone production.
  • Electrical insulation necessary for impulse transmission.
  • Waterproofing, eg. bird feathers and plant leaves.
33
Q

What are some important long-term energy storage roles of lipids, triglycerides in particular?

A
  • Thermal insulation to reduce heat loss
  • Cushioning to protect vital organs.
  • Buoyancy for aquatic animals.
34
Q

What test is used to identify lipids?

A

Emulsion test.

35
Q

What is the emulsion test?

A

A laboratory test for lipids using ethanol.

36
Q

How is a test for lipids carried out?

A

The sample is mixed with ethanol and the resulting solution is mixed with water and shaken.

37
Q

What is seen in a positive test for lipids?

A

A white emulsion forms as a layer on top of the solution.

38
Q

What is seen an a negative test for lipids?

A

The solution remains clear.

39
Q

What is food synergy?

A

The combined effect of a whole range of nutrients on a human’s health.