3.5 Electrons as Waves Flashcards
This scientist developed another explanation for the stability of electrons orbiting the nuclei of hydrogen atoms.
Louis de Brogile
Mass of an electron
9.109 x 10-31kg
De Broglie’s Equation
λ = h/mu
Where h is Planck’s constant
m is the mass of the particle
u is the speed
The wave associated with any moving particle
Matter Wave
The velocity of the electron in the ground state of the hydrogen atom is 3.00×106 m/s.
Using
λ = h/mu
6.626 x 10-34 / (9.109 x 10-31• 3.00x106)
= 2.42 x 10-10m
Calculate the de Broglie wavelength of a 142g baseball thrown at 44 m/s (98 mph).
Remember
1J = 1kg • m2/s2
142g = 0.142 kg
= (6.626 x 10-34J)/[(0.142)•(44)] = 1.06 x 10-34m
1.06 x 10-34m
A wave is confined to a given space, with a wavelength related to the length of space by L = n(λ/2).
Standing Wave
L the context of orbitals, nodes are locations at which electron density goes to zero.
Nodes
The principle that one cannot simultaneously know the exact position and the exact momentum of an electron.
Heisenberg uncertainty principle