3.4- ENERGY LEVELS IN ATOMS Flashcards

1
Q

What are the electrons of an atom trapped by?

A

electrostatic force of attraction of the nucleus

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2
Q

How do the electrons move about?

A

move about the nucleus in allowed shells/orbits, surrounding the nucleus

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3
Q

What is the energy of an electron in a shell closer to the nucleus like in comparison to an electron in a shell further away?

A

electron in a shell near nucleus has less energy than electron in shell further away from nucleus

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4
Q

What is an atoms ground state?

A

lowest energy state of an atom

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5
Q

What happens when an atom in the ground state absorbs energy?

A

one of its electrons moves to a shell at higher energy, so atom now in excited state

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6
Q

What can the excitation energy measurements be used to construct?

A

energy level diagram for the atom

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7
Q

What does an energy level diagram show?

A

the allowed energy values of the atom

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8
Q

What does each allowed energy of an energy level diagram correspond to?

A

certain electron configuration in the atom

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9
Q

If the ionisation level is considered as the zero reference level, what would the energy levels below it be like?

A

shown as negative values

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10
Q

What do gases at low pressure emit when they’re made to conduct electricity?

A

light

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11
Q

What does a neon tube emit when it conducts electricity?

A

red-orange light

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12
Q

What does the gas-filled tube used to measure excitation energies emit and when?

A

light when excitation occurs

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13
Q

Why is light emitted when excitation occurs in a gas-filled tube?

A

happens as the atoms absorb energy due to excitation by collision, but don’t retain the absorbed energy permanently

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14
Q

What is the electron configuration in an excited atom like?

A

unstable

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15
Q

Why is the electron configuration in an excited atom unstable?

A

an electron that moves to an outer shell leaves a vacancy in the shell it moves from

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16
Q

What happens to the vacancy in a shell when an electron moves from it?

A

vacancy filled by an electron from an outer shell transferring to it

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17
Q

What happens when the vacancy in a shell is filled by an electron from an outer shell transferring to it?

A

electron emits a photon

18
Q

What is the process of de-excitation?

A

atom moves to a lower energy level

19
Q

What is the energy of a photon emitted when an electron de-excites?

A

equal to energy lost by electron and so by atom

20
Q

Can an atom de-excite indirectly?

A

yes

21
Q

How can an atom de-excite indirectly?

A

via several energy levels if intermediate energy levels are present

22
Q

How is the energy of an emitted electron calculated?

A

energy of emitted electron hf = E1 - E2

23
Q

What can an electron in an atom do to move to an outer shell where vacancy exists?

A

absorb a photon

24
Q

What must the photon be like for it to be absorbed by an electron in an atom to move to an outer shell where vacancy exists?

A

energy of photons is exactly equal to gain in electron’s energy

25
Q

What happens if the photon energy needed by an electron in atom to move to an outer shell where vacancy is smaller or larger than the difference between the two energy levels?

A

will not be absorbed the electron

26
Q

In what ways can an atom in an excited state de-excite to ground state?

A

directly or indirectly, regardless of how excitation took place

27
Q

What can an atom absorb and emit?

A

photons of certain energies + emit photons of same/less energies

28
Q

What does the overall process of the atom exciting and de-exciting explain?

A

why certain substances fluorescence/ glow with visible light when they absorb UV radiation

29
Q

What do certain substance absorb? (fluorescence)

A

UV photons + become excited

30
Q

What does the atoms of the substance emit when they de-excite? (fluorescence)

A

emit visible photons

31
Q

What happens when the source of UV radiation is removed? (fluorescence)

A

substance stops glowing

32
Q

What is a fluorescence tube?

A

glass tube with a fluorescent coating on its inner surface

33
Q

What does the fluorescent tube contain?

A

mercury vapour

34
Q

What pressure is the mercury vapour at inside the fluorescent tube?

A

low pressure

35
Q

How does the ionisation + excitation of the mercury atoms within the fluorescent tube occur?

A

they collide with each other + with electrons in the tube

36
Q

What do the mercury atoms in the fluorescent tube emit when they de-excite?

A

UV photons, visible photons + photons of much less energy

37
Q

What happens to the UV photons emitted by the mercury atoms in the fluorescent tube?

A

UV photons absorbed by atoms of fluorescent coating

38
Q

What happens as the atoms of the fluorescent coating absorb the UV photons?

A

atoms become excited

39
Q

What do the coating atoms emit when they de-excite?

A

visible photons

40
Q

Is a florescent tube or filament lamp more efficient?

A

fluorescent tube more efficient

41
Q

How is a lot of energy wasted In a filament lamp?

A

heat energy