3.2.6 New Aqueous Ions Flashcards
Write a chemical equation for the reaction between [Fe(H2O)6]2+ and NaOH
[Fe(H2O)6]2++ 2OH⁻→ Fe(H2O)4(OH)2+ 2H2O
Write a chemical equation for the reaction between [Fe(H2O)6]2+ and NH3
[Fe(H2O)6]2++ 2NH3→ Fe(H2O)4(OH)2+ 2NH4+
Write a chemical equation for the reaction between [Fe(H2O)6]2+ and Na2CO3
[Fe(H2O)6]2+ + CO32⁻ → FeCO3+ 6H2O
Write a chemical equation for the reaction between [Fe(H2O)6]3+ and NaOH
[Fe(H2O)6]3++ 3OH⁻→ Fe(H2O)3(OH)3+ 3H2O
Write a chemical equation for the reaction between [Fe(H2O)6]3+ and NH3
[Fe(H2O)6]3++ 3NH3→ Fe(H2O)3(OH)3+ 3NH4+
Write a chemical equation for the reaction between [Fe(H2O)6]3+ and Na2CO3
2[Fe(H2O)6]3++ 3CO32⁻→ 2Fe(H2O)3(OH)3+ 3CO2+ 3H2O
Write a chemical equation for the reaction between [Al(H2O)6]3+ and NaOH
[Al(H2O)6]3++ 3OH⁻→ Al(H2O)3(OH)3+ 3H2O
Write a chemical equation for the reaction between [Al(H2O)6]3+ and excess NaOH
[Al(H2O)6]3++ 4OH⁻→ [Al(OH)4]⁻+ 6H2O
Write a chemical equation for the reaction between Al(H2O)3(OH)3 and excess NaOH
Al(H2O)3(OH)3+ OH⁻ → [Al(OH)4]⁻+ 3H2O
Write a chemical equation for the reaction between [A(H2O)6]3+ and NH3
[Al(H2O)6]3++ 3NH3→ Al(H2O)3(OH)3+ 3NH4+
Write a chemical equation for the reaction between [Al(H2O)6]3+ and Na2CO3
2[Al(H2O)6]3+ + 3CO32⁻→ 2Al(H2O)3(OH)3+ 3H2O + 3CO2
Write a chemical equation for the reaction between [Cu(H2O)6]2+ and NaOH
[Cu(H2O)6]2++ 2OH⁻→ Cu(H2O)4(OH)2+ 2H2O
Write a chemical equation for the reaction between [Cu(H2O)6]2+ and NH3
[Cu(H2O)6]2++ 2NH3→ Cu(H2O)4(OH)2+ 2NH4+
Write a chemical equation for the reaction between [Cu(H2O)6]2+ and excess NH3
[Cu(H2O)6]2++ 4NH3→ [Cu(H2O)2(NH3)4]2+ + 4H2O
Write a chemical equation for the reaction between Cu(H2O)4(OH)2 and excess NH3
Cu(H2O)4(OH)2+ 4NH3→ [Cu(H2O)2(NH3)4]2+ + 2H2O + 2OH⁻
Write a chemical equation for the reaction between [Cu(H2O)6]2+ and Na2CO3
[Cu(H2O)6]2+ + CO32⁻ → CuCO3+ 6H2O
Write a chemical equation for the reaction between [Cu(H2O)6]2+ and HCl
[Cu(H2O)6]2+ + 4Cl⁻ → [CuCl4]2⁻+ 6H2O
Which aqueous-ion solutions are the most acidic?
Solutions of [Fe(H2O)6]3+ and [Al(H2O)6]3+
Which aqueous-ion solutions are the least acidic?
Solutions of [Fe(H2O)6]2+ and [Cu(H2O)6]2+
Why are solutions of [Al(H2O)6]3+ acidic?
Al3+ is small and has a high charge. Al3+ polarises the O−H bonds in the H2O ligands, which weakens the O−H bonds (and allows H+ to dissociate)
Why are solutions of [Fe(H2O)6]3+ acidic?
Fe3+ is small and has a high charge. Fe3+ polarises the O−H bonds in the H2O ligands, which weakens the O−H bonds (and allows H+ to dissociate)
Why are solutions of [Al(H2O)6]3+ and [Fe(H2O)6]3+ more acidic than solutions of [CuH2O)6]2+ and [Fe(H2O)6]2+?
Al3+ and Fe3+ are smaller and have a higher charge than Cu2+ and Fe2+. Al3+ and Fe3+ polarise the water ligands more than Cu2+ and Fe2+, so the weaken the O−H bonds more (and dissociate more H+)
What coulour is aqueous [Fe(H2O)6]2+
Green solution
What is observed when NaOH is added to aqueous [Fe(H2O)6]2+?
Green solution forms a green precipitate (goes brown on standing in air)
What is observed when excess NaOH is added to aqueous [Fe(H2O)6]2+?
Green solution forms a green precipitate. No further change
What is the formula of the precipitate formed when NaOH is added to aqueous [Fe(H2O)6]2+?
Fe(H2O)4(OH)2
What is observed when NH3 is added to aqueous [Fe(H2O)6]2+?
Green solution forms a green precipitate (goes brown on standing in air)
What is observed when excess NH3 is added to aqueous [Fe(H2O)6]2+?
Green solution forms a green precipitate. No further change
What is the formula of the precipitate formed when NH3 is added to aqueous [Fe(H2O)6]2+?
Fe(H2O)4(OH)2
What is observed when Na2CO3 is added to aqueous [Fe(H2O)6]2+?
Green solution forms a green precipitate
What is the formula of the precipitate formed when Na2CO3 is added to aqueous [Fe(H2O)6]2+?
FeCO3
What reactants can be used to produce Fe(H2O)4(OH)2?
[Fe(H2O)6]2+ reacted with NaOH or NH3
What reactants can be used to produce FeCO3?
[Fe(H2O)6]2+ reacted with Na2CO3
Describe the appearance of Fe(H2O)4(OH)2
Green precipitate (goes brown on standing in air)
Describe the appearance of FeCO3
Green precipitate
What coulour is aqueous [Fe(H2O)6]3+
Purple solution (but looks brown due to some dissociation into [Fe(H2O)5(OH)]2+)
What is observed when NaOH is added to aqueous [Fe(H2O)6]3+?
Brown solution forms a brown precipitate
What is observed when excess NaOH is added to aqueous [Fe(H2O)6]3+?
Brown solution forms a brown precipitate. No further change
What is the formula of the precipitate formed when NaOH is added to aqueous [Fe(H2O)6]3+?
Fe(H2O)3(OH)3
What is observed when NH3 is added to aqueous [Fe(H2O)6]3+?
Brown solution forms a brown precipitate
What is observed when excess NH3 is added to aqueous [Fe(H2O)6]3+?
Brown solution forms a brown precipitate. No further change
What is the formula of the precipitate formed when NH3 is added to aqueous [Fe(H2O)6]3+?
Fe(H2O)3(OH)3
What is observed when Na2CO3 is added to aqueous [Fe(H2O)6]3+?
Brown solution forms a brown precipitate and effervescence (CO2 is released)
What is the formula of the precipitate formed when Na2CO3 is added to aqueous [Fe(H2O)6]3+?
Fe(H2O)3(OH)3
What reactants can be used to produce Fe(H2O)3(OH)3?
[Fe(H2O)6]3+ reacted with NaOH, NH3, or Na2CO3
Describe the appearance of Fe(H2O)3(OH)3
Brown precipitate
What coulour is aqueous [Al(H2O)6]3+?
Colourless solution
What is observed when NaOH is added to aqueous [Al(H2O)6]3+?
Colourless solution forms a white precipitate
What is observed when excess NaOH is added to aqueous [Al(H2O)6]3+?
Colourless solution forms a white precipitate that then dissolves to form a colourless solution
What is the formula of the precipitate formed when NaOH is added to aqueous [Al(H2O)6]3+?
Al(H2O)3(OH)3
What is the formula of the complex ion formed when excess NaOH is added to aqueous [Al(H2O)6]3+?
[Al(OH)4]⁻
What is observed when NH3 is added to aqueous [Al(H2O)6]3+?
Colourless solution forms a white precipitate
What is observed when excess NH3 is added to aqueous [Al(H2O)6]3+?
Colourless solution forms a white precipitate. No further change
What is the formula of the precipitate formed when NH3 is added to aqueous [Al(H2O)6]3+?
Al(H2O)3(OH)3
What is observed when Na2CO3 is added to aqueous [Al(H2O)6]3+?
Colourless solution forms a white precipitate and effervescence (CO2 is released)
What is the formula of the precipitate formed when Na2CO3 is added to aqueous [Al(H2O)6]3+?
Al(H2O)3(OH)3
What reactants can be used to produce Al(H2O)3(OH)3?
[Al(H2O)6]3+ reacted with NaOH, NH3 (not in excess), or Na2CO3
What reactants can be used to produce aqueous [Al(OH)4]⁻?
[Al(H2O)6]3+ reacted with excess NaOH
Describe the appearance of Al(H2O)3(OH)3
White precipitate
Describe the appearance of aqueous [Al(OH)4]⁻
Coourless solution
What coulour is aqueous [Cu(H2O)6]2+?
Blue solution
What is observed when NaOH is added to aqueous [Cu(H2O)6]2+?
Blue solution forms a blue precipitate
What is observed when excess NaOH is added to aqueous [Cu(H2O)6]2+?
Blue solution froms a blue precipitate. No further change
What is the formula of the precipitate formed when NaOH is added to aqueous [Cu(H2O)6]2+?
Cu(H2O)4(OH)2
What is observed when NH3 is added to aqueous [Cu(H2O)6]2+?
Blue solution forms a blue precipitate
What is observed when excess NH3 is added to aqueous [Cu(H2O)6]2+?
Blue solution forms a blue precipitate which then forms a deep blue solution
What is the formula of the precipitate formed when NH3 is added to aqueous [Cu(H2O)6]2+?
Cu(H2O)4(OH)2
What is the formula of the complex ion formed when excess NH3 is added to aqueous [Cu(H2O)6]2+?
[Cu(H2O)2(NH3)4]2+
What is observed when Na2CO3 is added to aqueous [Cu(H2O)6]2+?
Blue solution forms a blue-green precipitate
What is the formula of the precipitate formed when Na2CO3 is added to aqueous [Cu(H2O)6]2+?
CuCO3
What is observed when HCl is added to aqueous [Cu(H2O)6]2+?
Blue solution forms a yellow-green solution
What is the formula of the complex ion formed when HCl is added to aqueous [Cu(H2O)6]2+?
[CuCl4]2⁻
What reactants can be used to produce Cu(H2O)4(OH)2?
[Cu(H2O)6]2+ reacted with NaOH or NH3 (not in excess)
What reactants can be used to produce aqueous [Cu(H2O)2(NH3)4]2+?
[Cu(H2O)6]2+ reacted with excess NH3
What reactants can be used to produce CuCO3?
[Cu(H2O)6]2+ reacted with Na2CO3
What reactants can be used to produce aqueous [CuCl4]2⁻?
[Cu(H2O)6]2+ reacted with HCl
Describe the appearance of Cu(H2O)4(OH)2
Blue precipitate
Describe the appearance of aqueous [Cu(H2O)2(NH3)4]2+
Deep blue solution
Describe the appearance of CuCO3
Blue-green precipitate
Describe the appearance of aqueous [CuCl4]2⁻
Yellow-green solution