3.2.2 Reaction Rates Flashcards

1
Q

What’s the collision theory

A

For reactions to occur, particles must collide with each other with enough energy to break the bonds in the reactants

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2
Q

Why are only a small % of collisions successful

A

As there’s an energy barrier to breaking bonds

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3
Q

What do particles need to over come the barrier and react on collision

A

Enough energy (activation energy , Ea)

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4
Q

What are activation energies like for different reactions

A

Different

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5
Q

Define activation energy, Ea

A

Minimum amount of energy needed for a reaction to occur

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6
Q

What type of reaction has the most activation energy

A

Endothermic

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7
Q

What is the rate of reaction

+ equation

A

Change in concentration per unit time

Rate of reaction = amount of product produced/time taken

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8
Q

How could u work out the total number from a distribution curve

A

The area under the curve

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9
Q

What does the Maxwell-Boltzmann energy distribution curve show

A

The distribution of energies of particles in a gas

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10
Q

On Maxwell-Boltzmann energy distribution curve how many particles are at zero energy

A

0

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11
Q

On the Maxwell-Boltzmann energy distribution curve where does the curve never actually reach
Why

A

The x axis

As there will always be particles of very high energy

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12
Q

On the Maxwell-Boltzmann energy distribution curve what’s the area under the curve equal to

A

The total number of particles

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13
Q

What does the peak on a Maxwell-Boltzmann energy distribution curve indicate

A

The most probable energy (modal value/most common)

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14
Q

On Maxwell-Boltzmann energy distribution curve where’s the activation energy
What does this show you

A

The shaded bit to the left

Shows the amount of particles that can only react on collision

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15
Q

If temperature is increased what happens to the Maxwell-Boltzmann curve

A

Peak shifts to the right (higher energy)
Lower in height
Broader

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16
Q

On the M-B curve if temperature is increased, what are the particles like
So What’s the area under the curve like

A

Will be a general increase in number of particles at higher energies , but total number of particles is the same

Area under curve stays the same

17
Q

On the M-B curve with a temperature change , what’s the rate like

A

There’s a large increase in rate as there’s now many more particles (double) that possess an energy greater than activation energy

18
Q

What happens to the M-B curve if temperature is decreased

A

Curve moves left + peak is higher

19
Q

What are the particles on the M-B curve like when temperature is decreased
What happens to rate

A

1/2 number of particles possess activation energy

So rate of reaction decreases

20
Q

What does a catalyst do to activation energy

A

Lowers it

21
Q

What does the M-B curve look like when a catalyst is used

A

The same - no shape change + no change in energy of particles

22
Q

What happens to rate when a catalyst is added

A

Rate increases

As there are now more particles that have greater energy than activation energy

23
Q

What 4 factors affect rate of reaction

A

Temperature
Catalyst
Concentration
Pressure

24
Q

If temperature is increased, what happens to rate

A

Particle speed increases + more collisions occur
More kinetic energy

Rate of reaction is quicker -> amount of product produced is the same but it’s just produced quicker

25
Q

What does a catalyst do

A

Speeds up rate of reaction but is chemically unchanged at the end

26
Q

How does a catalyst work

A

Increases rate by providing an alternative reaction route of lower activation energy

27
Q

What happens to rate with higher concentration

A

Increases as there are more particles present in a given volume so there are more collisions

28
Q

What does increasing the pressure of a gaseous reaction do to rate

A

Increases rate as the particles are now forced closer together so collide more frequently

29
Q

When may pressure not increase the rate + product yield

A

If a gas reaction is in equilibrium (le chatelier’s principle)

30
Q

What are the 2 types of catalyst

A

Homogenous

Heterogenous

31
Q

What are homogenous catalysts

A

In the Same physical state as reactants e.g all liquids

32
Q

What are heterogenous catalysts like

E.g of process

A

In a different physical state to reactants

E.g haber process (solid catalyst, gaseous reactants)

33
Q

Why are catalysts important for the economy + sustainability

A

90% chemical materials made with catalysts
They lower Ea which reduces temperature required for reaction, so less fuel (fossil fuels) are needed reducing costs
Less CO2 (g) released into environment