3.1.7 ox,red+ redox eq (just things didnt know ) Flashcards
oxidation
process of electron loss , increase in oxygen number , gain of oxygen
reduction
process of electron gain , decrease in oxidation number, loss of oxygen
oxidising agent
one that accepts the electrons. it causes oxidation and gets reduced
reducing agent
one that donates the electrons . it causes the reduction and gets oxidised
oxidation number rules : group 1&2
group 1 = always +1
group 2 = always +2
oxidation number rules : aluminium , fluorine and chlorine
aluminium = always +3
fluorine = always -1
chlorine = -1 unless in compounds with F and O where it becomes positive
oxidation number rules : hydrogen, oxygen
hydrogen = +1 unless in metal hydrides where it’s is -1
oxygen = +2 unless in peroxide where it is -1 and if OF2 it is +2
half equations
show the transfer of electrons in a redox reaction
for the element oxidised :
_ -> _^+ + e-
for the element reduced :
_^- + e^- -> _
half equations for
CuO + Mg -> MgO + Cu
- Cu^2+ + 2e- -> Cu (reduced)
- Mg -> Mg^2+ + 2e- (oxidised)
balancing redox equations
1) write half equations for the reaction
2) make sure atoms are balanced
3) balance charges by adding electrons
4) multiply equations so number of electrons is the same in both reactions
5) combine both half equations
6) cancel out the electrons as they are the same on both sides
look at example slide 11
balancing redox equations in aqueous solutions
1) write half equations for oxidation and reduction
2) balance atoms apart from O and H
3) balance O by adding H20 molecules on other side of the equation
4) balance H by adding H+ ions on the other side of the equation
5) balance the charges on both half equations by adding electrons
6) make both half equations have the same number of electrons by multiplying whole equations
7) combine the equations together
8) cancel out the electrons (as they are equal)
9) cancel out things that are the same on both sides
look at example slide 13
half equations from balanced equation
1) put oxidation numbers above every element
2) increase in oxidation number = oxidised
3) decrease in oxidation number = reduced
4) write out equation for element oxidised from original equation
5) add electrons to equation
6) write out equation for the element reduced from original equation
7) add electrons to equation
8) if atoms don’t balance , add H+ ions or H20 molecules if in equation