3.1.3 The Halogens Flashcards

1
Q

What group are the halogens in

A

Group 7

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2
Q

What are the halogens

A

Non-metals that can consist of diatomic molecules

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3
Q

4 halogens to know and their halides

A

Fluorine, F2 - Flurodie, F-
Chlorine, Cl2 - Chloride, Cl-
Bromine, Br2 - Bromide, Br-
Iodine, I2 - Iodide, I-

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4
Q

What is fluorine, F2 in the form of at room temp

A

Pale yellow gas

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5
Q

What is Chlorine, Cl2 in the form of at room temp

A

Pale green gas

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6
Q

What is Bromine, Br2 in the form of at room temp

What colour vapour does it form

A

Dark red liquid and forms orange vapour

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7
Q

What is iodine, I2 in the form of at room temp

What vapour does it form

A

Grey solid

Forms purple vapour

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8
Q

Going down group 7, what happens to atomic radius

A

Gets larger as each element has 1 extra electron shell

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9
Q

What’s electronegativity

A

Measure of the ability of an atom to withdraw electron density in a covalent bond towards itself

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10
Q

What happens to electronegativity going down group 7

Why

A

Decreases

Due to increased shielding causing a weaker attraction by the nucleus

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11
Q

What happens to both melting and boiling point going down group 7
Why

A

Increases

As larger atoms have mor electrons making induced dipole-dipole forces between molecules stronger

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12
Q

What do oxidising agents like the halogens do

A

Accept electrons from another species

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13
Q

What’s the strongest oxidising agent of all the halogens

A

F2

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14
Q

What happens to the oxidising power going down a group

Why

A

It decreases
As the atomic radius increases + nuclear charge effect is reduced due to increased shielding

Larger halogens gain an electron less readily

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15
Q

What reactions are displacement reactions

A

Redox

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16
Q

How can a halogen displace another

A

If it’s a stronger oxidising agent

17
Q

What solution does bromine produce in a displacement reaction

A

Orange solution

18
Q

What solution does iodide produce in a displacement reaction

A

Violet/purple solution

19
Q

What’s the weakest oxidising agent of the halogens

A

Iodide, I2

20
Q

What halogen displaced both Br- and I-

A

Chlorine

21
Q

What halide will Br2 only displace

A

I-

22
Q

What 2 halogens both appear brown when forming solutions so it’s difficult to tell them apart

How can you distinguish between the two

A

Br2
I2

Distinguish by adding cyclohexane

23
Q

When cyclohexane is added to either Br2/I2 and shaken, what does it produce (2)

A

Orange layer - If Br2(aq)

Purple/violet layer - if I2 (aq)