3.1.3 Bonding Flashcards

1
Q

What are Compounds?

A

Compounds are Atoms of different Element Bonded together

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2
Q

What is Ionic Bonding?

A

When Ions are held together by Electrostatic Attraction

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3
Q

How are Ions formed?

A

Ions are formed when one or more electrons are transferred from one atom to another

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4
Q

Why does Sodium Chloride have a ‘Giant Ionic Lattice’ structure?

A

1) Ionic crystals are giant lattices of ions. A lattice is just a regular structure
2) Structure’s called ‘giant’ because its made up of the same basic unit repeated over and over again
3) In Sodium Chloride, the Na+ and Cl- ions are packed together. The Sodium Chloride lattice is Cube shaped – different ionic compounds have different shaped structures

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5
Q

How does Ionic Structure explain the Behaviour of Ionic Compounds?

A

1) Ionic Compounds conduct electricity when they’re molten or dissolved, but not when solid – Ions in liquid free to move. In solid they are fixed in position by strong ionic bonds
2) Ionic Compounds have high melting points – Giant ionic lattices held together by strong electrostatic forces. Takes lots of energy to overcome this hence high melting points (e.g 801˚C for Sodium Chloride)
3) Ionic compounds tend to dissolve in water – water molecules are polar, part of molecule slightly negative and other slightly positive. Charged parts pull ions away from Lattice, causing it to dissolve

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6
Q

What are molecules?

A

Molecules are Groups of Atoms Bonded Together

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7
Q

How are Molecules formed?

A

Form when two or more atoms bond together – it doesn’t matter if the atoms are same or different.
e.g. Cl2 (Chlorine Gas), CO (Carbon Monoxide), H2O (Water) and C2H5OH (Ethanol)

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8
Q

What hold molecules together?

A

Strong Covalent bonds

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9
Q

What does a single covalent bond contain?

A

A Shared Pair of Electrons

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10
Q

What do Giant Covalent structures have?

A

A Huge Network of Covalently bonded atoms (sometimes referred to as macromolecular structures)

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11
Q

Why is Carbon an example of Giant Covalent Structures?

A

Because they can each form 4 strong, covalent bonds.

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12
Q

What is Graphite?

A

An example of a Carbon Macromolecule with sheets of Hexagons with Delocalised Electrons

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13
Q

How does the structure of Graphite explain its properties?

A

1) Weak bonds between layers in graphite are easily broken, so sheets can slide over each other – graphite feels slippery so is used as a dry lubricant and in pencils
2) ‘Delocalised’ electrons aren’t attached to particular carbon atom and are free to move along the sheets carrying a charge. So Graphite is an electrical conductor
3) The layers are quite far apart compared to length of covalent bonds, so graphite has low density and used to make strong, lightweight sports equipment
4) Because of strong covalent bonds in hexagon sheets, graphite has very high melting point (sublimes @ over 3900K)
5) Graphite is insoluble in any solvent. Covalent bonds are too strong to break

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14
Q

What is Diamond?

A

Hardest Known Structure. Made up of Carbon atoms. Each Carbon Atom is covalently bonded to four other Carbon atoms. Atoms arrange themselves into tetrahedral shape

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15
Q

How does the Structure of Diamond explain its properties?

A

1) Very high melting point – sublimes @ over 3900K
2) Extremely hard – used in diamond-tipped drills and saws
3) Vibrations travel easily through stiff lattice, so its a good thermal conductor
4) Can’t conduct electricity – all outer electrons are held in localised bonds
5) Won’t dissolve in ANY Solvent (Insoluble)
6) You can ‘cut’ Diamond to form gemstones. Its structure makes it refract light a lot, which is why it sparkles

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16
Q

What are Dative Covalent Bonds (Co-Ordinate bond)?

A

Where both electrons come from one atom

17
Q

What is an example of Co-ordinate bonding?

A

Ammonium Ion (NH4+). Forms when Nitrogen atom donates a pair of electrons to a proton (H+)

18
Q

What does Molecular Shape depend on?

A

Electron Pairs (Lone Pairs) around Central Atom

19
Q

What do Bonding Pairs and Lone Pairs exist as?

A

Charge Clouds. It is an are where you have a really big chance of finding an electron pair. Electrons don’t stay still – they whizz around inside charge cloud

20
Q

Why do Electron Charge Clouds Repel Each Other?

A

1) Electrons are all negatively charged, so charge clouds will repel each other as much as possible. So pairs of electrons in outer shell will sit as far apart as possible
2) Shape of charge cloud affects how much it repels other charge clouds. Lone-pair charge clouds repel more than bonding-pair charge clouds
3) Greatest angles are between Lone Pairs of electrons, and bond angles between Bonding Pairs are reduced because they are pushed together by Lone-Pair Repulsion

21
Q

What are the different molecule shapes, electron pairs, lone pairs and bond angles?

A

2 Electron Pairs – No Lone Pairs, Linear, 180˚
3 Electron Pairs – No Lone Pairs, Trigonal Planar, 120˚
4 Electron Pairs (NLP) – Tetrahedral, 109.5˚
4 Electron Pairs (1LP) – Trigonal Pyramidal, 107˚
4 Electron Pairs (2LP) – Bent, 104.5˚
5 Electron Pairs (NLP) – Trigonal Bipyramidal, 90˚ and 120˚
5 Electron Pairs (1LP) – Seesaw, 102˚ and 87˚
5 Electron Pairs (2LP) – T-Shaped, 88˚
6 Electron Pairs (NLP) – Octahedral, 90˚
6 Electron Pairs (2LP) – Square Planar, 90˚