3.1.10 Equilibrium constant Kp for homogeneous systems Flashcards

1
Q

equation for calculating partial pressure

A

partial pressure=mole fraction of gas x total pressure

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2
Q

equation for mole fraction

A

mole fraction=no. of moles/total no. of moles of all gases

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3
Q

what is Kp

A

equilibrium constant

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4
Q

what does the Kp expression only include

A

gases

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5
Q

what does the p mean in Kp

A

partial pressure of that gas

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6
Q

how do you write an expression for Kp

A

p (products)-to the power of moles
divided by p (reactants) to the power of moles multiplied

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7
Q

what effect does a larger Kp value have

A

greater amount of products

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8
Q

if Kp is small, the equilibrium favours the…

A

reactants

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9
Q

what is the only thing that effects Kp or Kc

A

temperature

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10
Q

will a catalyst have any effect on the Kp value

A

no

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11
Q

what is the effect on the Kp value, if the forward reaction is exothermic and the temperature is increased

A

equilibrium will shift backwards in the endothermic direction
to oppose change
value of Kp gets smaller
as there are fewer products formed

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12
Q

in an equilibrium reaction there are fewer moles of gas on the product side, what effect does an increase in pressure on position of equilibrium and the Kp value?

A

equilibrium shifts to the forward direction, side with fewer moles of gas
to oppose the change in pressure
NO effect on Kp value as only temperature changes it

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13
Q

What does the effect of the addition of a catalyst on an equilibrium reaction

A

No change in Kp
Speeds up rate at which reaction reaches equilibrium

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