3.1.10 Equilibrium constant Kp for homogeneous systems Flashcards
equation for calculating partial pressure
partial pressure=mole fraction of gas x total pressure
equation for mole fraction
mole fraction=no. of moles/total no. of moles of all gases
what is Kp
equilibrium constant
what does the Kp expression only include
gases
what does the p mean in Kp
partial pressure of that gas
how do you write an expression for Kp
p (products)-to the power of moles
divided by p (reactants) to the power of moles multiplied
what effect does a larger Kp value have
greater amount of products
if Kp is small, the equilibrium favours the…
reactants
what is the only thing that effects Kp or Kc
temperature
will a catalyst have any effect on the Kp value
no
what is the effect on the Kp value, if the forward reaction is exothermic and the temperature is increased
equilibrium will shift backwards in the endothermic direction
to oppose change
value of Kp gets smaller
as there are fewer products formed
in an equilibrium reaction there are fewer moles of gas on the product side, what effect does an increase in pressure on position of equilibrium and the Kp value?
equilibrium shifts to the forward direction, side with fewer moles of gas
to oppose the change in pressure
NO effect on Kp value as only temperature changes it
What does the effect of the addition of a catalyst on an equilibrium reaction
No change in Kp
Speeds up rate at which reaction reaches equilibrium