3.1 Organic Chemistry Introduction Flashcards
Define empirical formula
Simplest whole number ratio of atoms in a molecule
Define molecular formula
Gives the actual number of atoms of different elements in a molecule
Define displayed formula
Shows every atom and every bond in a molecule
Define structural formula
Shows arrangement of atoms in a molecule without showing every bond
Define skeletal formula
Drawn as lines with each vertex being a carbon atom. Carbon atoms not drawn, assumed each C atom has all unspecified bonds as C-H
Define structural isomerism
When molecules have the same molecular formula but different structural formula
What is positional isomerism?
Functional group is attached to the main chain at a different place
What is functional group isomerism?
Same atoms but different functional group due to a different arrangement of atoms
What is chain isomerism?
Hydrocarbon chain organised differently e.g. branched chains
Define stereoisomerism.
When molecules have the same structural and molecular formula, but different arrangement of atoms in space
What is E-Z isomerism and how are the E and Z isomers decided?
E-Z isomerism is caused by the limited rotation about C=C double bonds.
If the twp substituents with the highest molecular mass are on the same side of the double bond, it is the Z (zusammen) isomer.
If they are on different sides, it is the E (entgegen) isomer.