3.1 Introduction To Organic Flashcards

1
Q

Define empirical formula

A

Simplest whole number ratio of atoms in a molecule

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2
Q

Define molecular formula

A

Gives the actual number of atoms of different elements in a molecule

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3
Q

Define displayed formula

A

Shows every atom and every bond within a molecule

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4
Q

Define structural formula

A

Shows the arrangement of atoms in a molecule without showing every bond

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5
Q

Define structural formula

A

Drawn as lines with each vertex being a carbon atom. Carbon atoms not drawn, assumed each C atom has all unspecified bond such as C-H

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6
Q

Give the suffixes for:
A) No double bonds
B) At least one double bond
C) An alcohol
D) An aldehyde
E) A ketone
F) A carboxylic acid

A

A) -ane
B) -ene
C) -ol
D) -al
E) -one
F) -oic acid

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7
Q

Give the prefixes for:
A) CH3
B) C2H5
C) C3H7
D) C4H9
E) Cl group
F) Br group
G) I group

A

A) Methyl-
B) Ethyl-
C) Propyl-
D) Butyl-
E) Chloro-
F) Bromo-
G) Iodo-

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8
Q

Define structural isomerism

A

When molecules have the same molecular formula but different structural formula

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9
Q

What is positional isomerism?

A

Functional group is attached to the main chain at a different place

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10
Q

What is functional group isomerism

A

Same atoms but a different functional group due to a different arrangement of atoms

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11
Q

What is chain isomerism

A

Hydrocarbon chain organised differently - e.g. branched chains

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12
Q

Define sterioisomerism

A

When molecules have the same structural and molecular formula, but have a different arrangement of atoms in space

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13
Q

What is E-Z isomerism and how are the E or Z isomers decided

A

E-Z isomerism is caused by the limited rotation about C=C double bonds
If the two substituents with the highest molecular mass are on the same side of the double bond it is the Z (Zusammen) isomer
If they are on different sides then it is the E (Entgegen) isomer

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