3- Structure Of Matter + Polymer Chemistry Flashcards
Adhesion
Unlike molecules attracted
Cohesion
Like molecules attracted
Adhesive
Material used to cause adhesion
Adherend
Material that adhesive is applied to
Tarnish
Metal surface loses its lustre when a chemical reaction causes a thin film to form
Occurs following formation of deposits on a surface (Ex. Micro-organism film)
Corrosion
Metal attacked by environmental agent and begins to dissolve
Dry/Chemical Corrosion
Direct combination of metallic/non-metallic elements to yield a chemical compound
No water
Ex. Oxidation
Wet/Electrochemical Corrosion
Requires water or electrolytes
Involves transfer of electrons from one material to another
Fillers
Increases Young’s modulus/rigidity- will not deform under stress
Plasticizers
Small molecules added to soften a polymer
Factors Affecting Crystallinity
Chain length and flexibility (double bonds can’t rearrange- prevents close packing)
Side chains
Intermolecular forces- self assembly of polymers
Properties of Dental Resins
Mechanical
Rheometric
Salvation
Thermal
Factors Affecting Tm and Tg
Crystallinity (harder to break bonds= higher Tg) Chain stiffness (increases Tm and Tg) Side groups, polar groups, double bonds, aromatics- increase Tg (more amorphous= higher Tg)