3: Redox I Flashcards

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1
Q

What are the definitions of oxidation

A
  • Addition of oxygen
  • Loss of hydrogen
  • Loss of electrons
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2
Q

What are the definitions of reduction

A
  • Loss of oxygen
  • Addition of hydrogen
  • Gain of electrons
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3
Q

What is OILRIG

A

Oxidation is loss of electrons, reduction is gain of electrons

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4
Q

What is oxidation number

A

The charge that would exist on an individual atom if the bonding were completely ionic

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5
Q

What is the oxidation number of uncombined elements

A

0

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6
Q

What is the oxidation number of a cation

A

+ (charge)

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7
Q

What is the oxidation number of an anion

A
  • (charge)
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8
Q

What do roman numerals indicate

A

The oxidation state of ions in a compound

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9
Q

What is the oxidation state of a mono-atomic atom (e.g. Zn+2)

A

The same as the charge on the ion (e.g. +2)

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10
Q

What is the sum of the oxidation numbers in a compound (e.g. NaCl)

A

0

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11
Q

What is the sum of oxidation in an ion (e.g. SO4-2)

A

Equal to the charge (e.g. -2)

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12
Q

What is given the oxidation number in compounds or ions

A

The more electronegative element is given the negative value

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13
Q

What is the oxidation state of group 1 elements

A

Always +1

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14
Q

What is the oxidation state of group 2 elements

A

Always +2

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15
Q

What is the oxidation state of fluorine

A

Always -1

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16
Q

What is the oxidation state of hydrogen

A

+1 (except in metal hydrides where it’s -1)

17
Q

What is the oxidation state of oxygen

A

-2 (except in peroxides where it’s -1, and F2O where it’s +2)

18
Q

What is the oxidation number in molecules or compounds

A

The sum of the oxidation numbers is 0

19
Q

How do you determine the element with a positive oxidation state in a molecule/compound

A

The more electronegative value has the negative value

20
Q

How to determine the oxidation number

A
  • Group in periodic table
  • Other elements in formula
  • Following oxidation rules
  • Certain species can have varying oxidation states!
21
Q

How can oxidation and reduction in terms of electron transfer be demonstrated

A
22
Q

What is an oxidising agent

A

A substance that oxidises another atom/ion by causing it to lose electrons, whilst itself gaining electrons and being reduced. Its oxidation number becomes more negative

23
Q

What is a reducing agent

A

A substance that reduces another atom/ion by causing it to gain electrons, whilst itself losing electors and being oxidised. It’s oxidation number becomes more positive

24
Q

What is a redox reaction

A

Oxidation and reduction must occur, there is both a reducing and oxidising agent present

25
Q

How to determine the strongest oxidising/reducing agent

A

The species which oxidation number changes the most dramatically

26
Q

What is a disproportionation reaction

A

A reaction in which the same species is simultaneously oxidised and reduced

27
Q

How to balance disproportion reactions

A
  • Deduce oxidation number changes
  • Balance oxidation number changes
  • Balance charges
28
Q

What are the usual oxidation states of metals

A
  • Positive values in compounds
  • Value usually that of the group number
  • With several oxidation number possibilities the value is no higher than the group number
  • Generally oxidised
29
Q

What are the usual oxidation numbers of non-metals

A
  • Mostly negative based on usual ions
  • Can have values up to their group number
  • Generally reduced
30
Q

How to write and balance full ionic equations

A