3. Quantum Physics - short questions Flashcards
Describe the Thomson model.
Thomson model describes the atom as a sphericaly, positivly charged volume embedded with electrons.
Describe the Planetary model. Who were the authors? What was the problem of this model?
The authors were Nagaoka and Rutherford.
There is a small positively charged volume called nucleus and the electrons are around it in a large volume.
Especially in the Nagaoka model, the frequency of the electron should vary continously leading to the collaps of the elctrons. That’s why this model could not explain the spectral emissions.
Describe the 4 points of the Bohr’s model.
- Electrons move in circular orbits and only some of them are stable
- The allowed orbits are those for which the angular momentum of the orbital of the electron is quantized. Thus the for the stable orbits holds:
mvr=nh_bar
- The centrifugally accelerated electrons cannot continously emit radiations since the enegy is quantized.
An atom emits radiations when an electron performs a transition from a higer-energy state to a lower-energy state.
The frequency of the emitted photon is related to the energy of the levels of the transition and it is not equal to the energy of the electron’s orbital motion - The frequency
v
of the emitted radiation comes from the conservation of energyE_f - E_i = hv
h_bar = reduced Plank’s constant or Dirac’s constant AND v = frequency
Bohr combined 3 theories to create his model. State them.
Plank’s quantum theory, photoelectric effect explained by Einstein in 1905, Rutherford planetary model.
The formula mvr=nh_bar
describes one of the 4 points of the Borh’s model. State it.
h_bar = reduced Plank’s constant or Dirac’s constant
The allowed orbits are those for which the angular momentum of the orbits of the electron is quatized.
State the Schrodinger equation.
In the Schrodinger equation, in which case the solution of the eq. depends only on one variable? Which variable is?
If there is no external magnetic field, the Schrodinger equation depends only on the quantum number n and we get the new formulation of energy:
~~~
E = (-13.6Z^2)/n^2
~~~
The atomic models must study..
The discrete emission of light.
The Stern-Gerlach experiments proved.. (2 results)
- the space-quantisation assosciated with the orbital angular momentum of the electron
- the anomalous Zeeman effect
Zeeman measured..
The splitting spectral lines by a strong magnetic field
Which is the difference between the normal and the anomalous Zeeman effect?
In the normal Zeeman effect the spectral lines appears with 2 other lines.
In the anomalous Zeeman effect, the spectral lines appears with several other lines
The Bohr-Sommerfeld model predicted an odd number of ..(1).. because ..(2)..
1) components in the deflected beam
2) there should be 2l+1 orientations and l is a natural number
What did the Bohr-Sommerfeld model predicted and in which occasion it has been found a contraddiction of it?
The Bohr-Sommerfeld model predicted an odd number of odd components in the deflected beam since there should be 2l+1 orientations and l is a natural number, but this is not always true because in the case of the Stern-Gerlach experiment.
An example of contraddiction is the anomalous Zeeman effect.
Describe the Ster-Gerlach experiment and its result.
A beam of silver particles is sent towards a non-uniform magnetic field and the deflected beam is split into 2 discrete components.
If the magnetic field B is in the z-direction, the magnetic force will be proportional to the magnetic moment mu_z
.
What do we expect as a result of the Stern-Gerlach experiment from a classical point of view? What did the experimental result showes?
- From classical pov: since
mu
can have any orientation, we expect the deflected beam to be spread out continously. - From experimental results and according to quantum mechanics, the deflected beam is splitted in a number of discrete components, so space-quantisation is proved.