3-Periodic Table and Energy Flashcards
Periodicity
the repeating trend in properties of the elements across a period
First ionisation energy
The energy required to remove one electron from each atom in one mole of gaseous atoms of an element to form one mole of gaseous 1+ ions
Factors affecting ionisation
Atomic radius - the greater the distance between the nucleus and the outer shell the less the nuclear attraction, so much lower ionisation energy
Nuclear charge - more protons in the nucleus the greater the attraction between nucleus and outer electrons, so higher ionisation energy
Electron shielding - inner-shell electrons repel outer shell electrons which reduces the attraction between the nucleus and outer electrons.
Trend in first ionisation energy across a period
General increase in first ionisation energy; nuclear charge increases, shell stays the same, so nuclear attraction increase, atomic radius decreases and so the first ionisation energy increases
A sharp decrease between the end of one period and the start of the next period; increased shell number so larger atomic radius and more shielding
Trend in first ionisation energy down a group
Decrease down a group; the nuclear charge increases but the effect is outweighed by the increased radius and the increased shielding