3. Halogenoalkanes Flashcards

1
Q

why is halogenoalkanes used as flame retardants and anaesthetics?

A

Unlike some of the elements from which they are formed, such as fluorine and chlorine, many halogenoalkanes are relatively unreactive under normal conditions which leads to their use as flame retardants and anaesthetics.

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2
Q

what was an early anaesthetic?

A

chloroform.

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3
Q

what was the systematic name of chloroform?

A

trichloromethane

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4
Q

Nowadays you may receive a gas called what as an anaesthetic?

A

halothane

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5
Q

what is the condition of halogenoalkanes under normal and other other conditions?

A

under normal conditions- relatively unreactive

other conditions, such as high in the Earth’s stratosphere- react in completely different ways

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6
Q

alkenes undergo addition reactions with reagents such as

A

bromine and HBr

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7
Q

Haloalkanes are derivatives of

A

alkanes

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8
Q

We can consider all haloalkanes to be members of a class of compounds and expect them all to show what?

A

similar properties and behaviour

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9
Q

If we consider how readily a haloalkane undergoes a particular reaction, we find that it depends on

A

the nature of both the alkyl group and the halogen

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10
Q

the conversion of a haloalkane, R–X, to an alcohol, R–OH, can be carried out using what?

A

using hydroxide ions from NaOH in a suitable solvent

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11
Q

the rate of the reaction of the conversion of a haloalkane, R–X, to an alcohol, R–OH using hydroxide ions from NaOH in a suitable solvent varies very considerably, depending on

A

the nature of the alkyl group R and on whether X is I, Br, Cl or F

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12
Q

Halogenoalkanes have the general formula

A

CnH2n+1X or RX

where X is a halogen

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13
Q

halogenoalkanes may be classified according to what?

A

the position of the halogen functional group in a similar way to alcohols

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14
Q

how would halogenoalkanes may be classified according to the position of the halogen functional group in a similar way to alcohols

A

primary halogenoalkane
secondary halogenoalkane
tertiary halogenoalkane

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15
Q

Halogenoalkanes behave differently depending on what?

A

on which other groups are attached to the carbon that the halogen is attached to

(you will see this trend with other functional groups)

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16
Q

a primary halogenoalkanes is when

A

the halogen is bonded to a carbon, which is itself only attached to one other carbon atom

17
Q

a secondary halogenoalkanes is when

A

the halogen is bonded to a carbon that is itself attached to two other carbon atoms

18
Q

a tertiary halogenoalkanes is when

A

the halogen is bonded to a carbon that is itself attached to three other carbon atoms

19
Q

exceptions of Primary halogenoalkane are

A

halomethanes

20
Q

The C-Hal bond is polar due to?

A

the difference in electronegativity between the carbon atom and the halogen atom