2b Flashcards

1
Q

what is oxidation

A

conversion of a functional group in another one with a higher oxidation state or level

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2
Q

reduction

A

conversion of a functional group in another one with a lower oxidation level or state

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3
Q

reduction does what to an oxidation level

A

reduces the value
the value gets smaller

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4
Q

what does oxidation do to an oxidation level

A

increases the oxidation level or state

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5
Q

what is a heteroatom

A

anything but a C or H

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6
Q

how many levels of oxidation levels/states are there

A

5 in total
0,1,2,3,4

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7
Q

whats a 0 oxidation level

A

carbons are bonded to 0 more electronegative atoms

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8
Q

level 0 oxidation level examples

A

methane
alkanes

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9
Q

what is level 1 oxidation level

A

C is bonded to 1 more electronegative element

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10
Q

level 1 oxidation state examples

A

alkene
alcohol
halogenoalkanes

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11
Q

level 2 oxidation level

A

carbon is bonded to 2 more electronegative atoms

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12
Q

level 2 oxidation level examples

A

ketone
alkyne (c triple c)
aldehyde

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13
Q

level 3 oxidation level

A

carbon bonded to 3 more electronegative elements

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14
Q

levels 3 oxidation level examples

A

carboxylic acid
amides
nitriles

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15
Q

level 4 oxidation level

A

carbon is bonded to 4 more electronegative elements

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16
Q

level 4 oxidation level examples

A

o=c=o
s=c=s

17
Q

resonance structure rules

A
  • have the same number of valence electrons
  • octet rule must be obeyed
  • nuclei do not change positions in space between resonance structures
18
Q

what do resonance structures differ in

A

they differ in the arrangement of valence electrons

19
Q

what is special about c=o

A

the c and o are electrophilic and basic respectively.

c is electrophilic
o is basic

20
Q

what does the c react with

A

nucleophiles bc it has a partial positive charge

21
Q

what does the o react with

A

lewis acids

things that accept electrons

22
Q

if o interacts with lewis acids it must be a

A

weak lewis base
donates electrons

23
Q

what is the alpha carbon

A

the carbon next to the carbonyl group

the carbon near the c=o

24
Q

the alpha carbon is usually bonded to what

A

the carbonyl group
alpha Hydrogens

25
Q

what are special about alpha Hydrogens

A

theyre bonded to the alpha carbon

they are more acidic than alkane hydrogens

26
Q

removal of the alpha hydrogens via deprotonation will give what

A

it will give an anion (-)

27
Q

deprotonation of a alpha hydrogen will give an anion,, how can these be stabilised

A

through delocalisation aka resonance?

the (-) formed by protonation is delocalised over the pi system (c=o) and is ultimately placed on the more electronegative Oxygen atom

28
Q

what shape is c=o

A

its planar

29
Q
A