2.8.1 Enthalpy Changes Flashcards
What does ‘enthalpy’ mean?
Enthalpy is the term used to describe the heat energy content of a system
What is H?
H is enthalpy change
How can enthalpy change be calculated?
It can be calculated from measuring changes in temperature
What is enthalpy change defined as?
‘The heat energy change under measured conditions of constant pressure’
What does H equal?
H = H(products) - H(reactants)
What sign is the H if the reaction is exothermic?
-H
What sign is the H if the reaction is endothermic?
+H
What is standard pressure?
100kPa
What are the conditions for standard enthalpy change?
- 100kPa
- the substances are in their standard States
What are the units for H?
KJmol-1
What is the definition of standard enthalpy change of formation?
The enthalpy change when a molecule or compound is formed from its elements in their standard states
What is the equation for the formation of magnesium oxide?
Mg(s) + 1/2O2(g) ➡️ MgO(s)
What is the definition for enthalpy change of combustion?
The enthalpy change when one mole of substance is completely burned in oxygen under standard conditions
What is the equation for the combustion of ethane?
C2H6(g) + 7/2O2(g) ➡️ 2CO2(g) + 3H2O(l)
What do chemical reactions involve?
- the breaking of bonds between atoms
- the making of new bonds between atoms