2.3 Group 7 Flashcards
Atomic Radius
increases
more energy levels
Ionization Energy
decreases
more energy levels
larger radius, less shielding
less attraction of valence e and nucleus
Electronegetivity
decreases
more energy levels
larger radius, less shielding
less attraction of valence e and nucleus
Boiling Point
Increases
larger molecules, stronger vdw between molecules
need more energy to overcome
Reaction (displacement) with conc H2SO4
NaX+H2SO4–> NaHSO4 +HX
Halide Test
+HNO3 (displace CO3 ions)
+NaOH (neutralize)
+AgNO3 (f dissolve, cl white, br cream, I yellow)
+dilute/conc NH3
Making Bleach
Cl2+2NaOH NaClO+ NaCl+H2O
Reaction (reduction) with conc H2SO4
SO4–> SO2/S/H2S
Product Identification of reaction with H2SO4
HX (misty fume) Br2 (orange gas) I2 (purple gas/black solid) SO2 (colourless, toxic) S (yellow solid) H2S (rotten egg smell)
Cl in water
Cl2+H20 –> HClO+HCl
Colours!!!
F2 (pale yellow, react with water)
Cl2 (green, pale green dissolved)
Br2 (red/brown, orange dissolved)
I2 (grey, brown dissolved)