2.2 Group 2 Flashcards
first ionisation energy equation of magnesium
Mg (g) -> Mg+ (g) + e-
trend of ionisation energy down group 2
decreases.
atomic radius increases as there are more electron shells which also increases shielding.
less energy required for the outer electron to be removed
trend of atomic radius down group 2
increases.
more electron shells.
increased shielding.
outer electrons are further away from the nucleus.
weaker electrostatic attraction.
trend of melting point down group 2
decreases.
metallic bond gets weaker as you go down the group.
as atomic size increases.
the distance between the nucleus and the electrons gets bigger.
electrostatic force of attraction between positive ions and delocalised electrons gets weaker.
less energy required to break the bonds.
reactivity down group 2
reactivity increases.
as electrons get further away from the nucleus.
easier to react with other elements.
form 2+ ions
group 2 reactions with oxygen
solid white oxide forms
form MgO
group 2 reactivity with water
reactivity increases down the group.
fizzing, metal dissolving and heating up of solution is observed.
magnesium reaction with water + steam
water: produces magnesium hydroxide Mg(OH)2
slow reaction
steam: produces magnesium oxide MgO
burns with a bright white flame
trend of solubility of hydroxides down group 2
solubility increases down the group.
Mg is insoluble + Ba is soluble.
trend of solubility of sulfates down group 2
solubility decreases down the group.
magnesium is soluble
barium is insoluble
magnesium in titanium
TiO2 is converted to TiCl4
TiCl4 is purified through fractional distillation
Ti is extracted by Mg
equations for the extraction of titanium
1) TiO2 + 2Cl2 + 2C ->
TiCl4 + 2CO
2) TiCl4 + 2Mg ->
Ti + MgCl2
use of magnesium hydroxide
used as an antacid to treat indigestion
use and equation of calcium hydroxide
used to neutralise soil
Ca(OH)2 + CO2 -> H2O + CaCO3
use of calcium oxide and calcium carbonate + equations
remove SO2 from flue gases.
CaO + SO2 ->
CaSO3
CaCO3 + SO2 ->
CaSO3 + CO2