2.1.2 biological molecules Flashcards
why is water important
- all metabolic reactions in cells take place in water (cytoplasm, vacuole/sap)
- 71% of the earth’s surface is covered in water, making it a major habitat
- 70-95% of a cell’s mass is water
what are hydrogen bonds and how do they form
- as a result of the polarity of molecules such as water, the
what is the charge of a water molecule
- electrically neutral as a whole, but is a dipole, polar molecule
- the oxygen atoms are more electronegative than hydrogen, resulting in a weak negative electric charge as they attract electrons more strongly (δ-)
- hydrogen is electronegatively weaker than oxygen, forming a slight positive charge (δ+)
- this means that the covalently shared electrons are closer to the oxygen atom (polar covalent bond)
what is the shape of a water molecule
- due to waters polarity, its shape is asymmetrical
- there is about 105 degrees between the hydrogens
what are hydrogen bonds and where/how do they form
- hydrogen bonds form between the δ+ and δ- ends of polar molecules such as water
- they are weak by themselves, so constantly break and reform, but form strong structures when in larger numbers
what are the main properties of water
- a universal solvent (will be able to dissolve any polar molecule)
- acts as a transport medium
- has a high specific heat capacity
- has a high latent heat of vaporisation
- less dense in solid form (ice floats on water, which provides an insulating layer and acts as a habitat for animals e.g. polar bears, underwater flora)
- high surface tension (adhesion) and cohesion (transpiration stream)
- can act as a reagent
why is water a good solvent and what does it allow
- as it is polar, many polar substances and ions can dissolve in it as they compete with hydrogen bonds
- e.g. Na+ and Cl- ions, glucose, amino acids
- this allows chemical reactions to occur within cells (as the dissolved solvents are more reactive as they are free to move in aqueous form)
- hydrophilic (polar) metabolites (chemical substances involved in metabolism) can be transported efficiently
- prokaryotes can exchange nutrients and waste substances with their surroundings via diffusion
why does water have a high SHC and what does it allow
- has a specific heat capacity of 4200 J/kg°C
- the many hydrogen bonds between the polar molecules require a lot of thermal energy to break and a lot of energy to build
- this means that water temperature does not fluctuate greatly or very quickly
- this provides a stable habitat for aquatic organisms in lakes and oceans, and maintains temperatures that are optimal for enzyme activity in both prokaryotes and eukaryotes
- water in blood plasma helps to transfer heat around the body, as thermal energy is absorbed, but does not change temp much
- water is also in tissue fluid, playing a role in maintaining constant body temperature
why does water have a high latent heat of vaporisation and what does it allow
- a large amount of thermal energy has to be absorbed to break hydrogen bonds to cause the molecules to evaporate
- only a small amount of water needs to be lost by organisms to lose a lot of thermal energy
- provides a cooling effect for living organisms (thermal energy lost due to sweat evaporation, transpiration through stomata in leaves)
what is cohesion and what does it allow
- hydrogen bonds between the δ+ (hydrogen) and δ- (oxygen) ends of water molecules on the surface of the water
- this provides strong surface tension on water, meaning many small invertebrates (pond skaters etc.) can float
- cohesion also allows water to move through xylem and blood vessels, as water can climb up to 1m in tubes (the smaller the diameter of the tube, the higher it can climb)
what is adhesion and what does it allow
- hydrogen bonds/intermolecular associations between water and other molecules (such as cellulose and lignin)
- allows movement up the transpiration stream as the water adheres to the lignin walls of xylem
what elements are in carbohydrates and what is their general formula
- Carbon, Hydrogen, Oxygen
- Cx (H2O)y
Lipids consist of…
Carbon, Hydrogen, Oxygen, sometimes Phosphorus (however has very little Oxygen compared to carbs)
nucleic acids consist of…
Carbon, Hydrogen, Oxygen, Nitrogen, Phosphorus
proteins consist of…
Carbon, Hydrogen, Oxygen, Nitrogen, Sulfur
carbohydrates- monomers and polymers
monosaccharides (glucose, fructose, galactose)
di/polysaccharides (starch, cellulose)
proteins- monomers and polymers
peptides/amino cids
polypeptides
lipids- monomers
phosphates, fatty acids, glycerol
nucleic acids- monomers and polymers
nucleotides (deoxy/ribose sugar + phosphate + nitrogenous base)
DNA, RNA
what is a condensation reaction
when monomers join together to form a polymer or macromolecule, releasing water and making a covalent bond- can be catalysed by enzymes