2.1.1-Atomic structure and isotopes Flashcards

1
Q

relative isotopic mass

A

mass of an isotope compared to 1/12th of mass of an atom of carbon-12

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2
Q

relative atomic mass-Ar

A

weighted mean mass of an atom of an isotope compared to 1/12th of mass of an atom of carbon-12

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3
Q

what does the weighted mean mass take into account

A

-mass of each isotope
-percentage abundance of each isotope
-so number in periodic table

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4
Q

relative molecular mass use

A

in covalent molecules

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5
Q

relative formula mass

A

for ionic compounds and other giant structures

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6
Q

how to calculate relative molecular or formula masses

A

adding all the Mr’s

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7
Q

isotopes

A

atoms of the same element with the same number of electrons and protons but different number of neutrons and different masses

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8
Q

describe why isotopes have similar chemical properties

A

-have same number of electrons in their shells
-as an atom of that element and their arrangement is same

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9
Q

what is the standard element that all elements are compared to

A

carbon-12

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10
Q

use of mass spectrometer

A

to determine the relative isotopic masses and relative abundances of isotopes

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11
Q

relative molecular mass-Mr

A

the mean mass of a molecule compared to 1/12th of mass of an atom of carbon-12

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12
Q

Atom economy for each reaction type

A

addition reaction -100 percent
substitution -less
elimination-less

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13
Q

decomposition reaction

A

one reactant broken apart into multiple reactions

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14
Q

detector in mass spectrometry

A

-electric or photographic detection methods

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14
Q

how are percentage abundances in isotopes found w mass spectrometer

A

1-sample placed in mass spec,vapourised to form +ve ions
2-ions accelerated-heavier move more slowly and difficult to detect so ions of different isotopes separated
3-ions detected as a mass to charge ratio-m/z
greater the abundance he greater the signal

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15
Q

How to calculate number of protons neutrons and electrons for neutral atoms and ions?

A

neutral atoms
number of elec=number of protons
number of neutrons =mass number - atomic number

ions
number of electrons less than number of protons-+
number of electrons more than number of protons- -
charges affect ions

16
Q

how to get moles of unkown chemical

A

mole ratio

16
Q

how to work out relative formula or molecular mass?

A

add up all the mass numbers

17
Q

limiting reagent vs excess reagent

A

limiting reagent
-limits maximum/theoretical amount of product that can form
-is the reacttant totally used up in a reaction

excess reagent
-has some left over after reaction

17
Q

mass number and atomic number

A

mass number = number of protons and neutrons

atomic number= number of protons

18
Q

solute and solvent

A

solute-substance being dissolved
solvent-dissolved in most commonly H2O

18
Q

state equation for hydrated salt CuSO4 .5 H2O being heated

A

CuSO4 .5 H2O ———- CuSO4 + 5H2O

-when hydrated salts are heated,the water driven off and compound left is referred to as the anhydrous salt

19
Q

state why group 0 do not form ions

A

-noble gases are non metals
-already have full outer energy level which other atoms strive to have.

19
Q

what does mass spectrometer consist of

A

ion source
analyser
detector

20
Q

what does the mass number and atomic number determine

A

mass number-physical properties
protons and neutrons
atomic number-chemical properties
protons

20
Q

what happens to chemical activity in isotopes?

A

-does not change
-chemical activity determined by atomic number which is number of protons that does not change
-as isotopes have same number of protons and electrons

21
Q

what solutions dont have an impact on dry litmus paper

A

when no aqueous hydrogen ions present
if present of H+ ion turns red