2.1 Flashcards
How is the term “pure” defined in chemistry?
In chemistry, a pure substance consists of a single element or compound with no other substances mixed in
What distinguishes a mixture from a pure substance in chemistry?
Answer: A mixture consists of two or more elements or compounds physically mixed together without chemical bonding, while a pure substance contains only one element or compound.
What happens to the chemical properties of substances in a mixture?
Answer: The chemical properties of substances in a mixture remain unchanged because they are not chemically combined.
: How can substances in mixtures be separated?
Answer: Substances in mixtures can be separated by physical means, such as filtration, distillation, or chromatography
what distinguishes a pure substance from a mixture?
A mixture, on the other hand, consists of two or more elements or compounds physically mixed together without chemical bonding.
How can substances in mixtures be separated, and what remains unchanged in a mixture?
Substances in mixtures can be separated by physical means, such as filtration or distillation. The chemical properties of the substances in a mixture remain unchanged because they are not chemically combined
How do melting and boiling point data help distinguish between pure substances and mixtures?
Pure substances melt and boil at specific and sharp temperatures, while mixtures have a range of melting and boiling points due to the presence of different substances. Melting point analysis is routinely used to assess the purity of substances, with closer measured values indicating higher purity.
What does a cooling curve reveal about the purity of a substance?
Answer: A cooling curve for a pure substance shows a sharp melting point, indicating purity. However, an impure substance produces a gradual decrease in temperature as it freezes, showing impurities present.
How is percentage change calculated, and why is it commonly used in purity assessments?
Answer: Percentage change is calculated by dividing the difference between two values by the original amount, then multiplying by 100. It is commonly used in purity assessments to quantify the degree of change in a substance’s properties due to impurities
Question: What is the empirical formula?
Answer: The empirical formula is the simplest whole number ratio of atoms of each element in a molecule.
Question: How does the molecular formula differ from the empirical formula?
Answer: The molecular formula tells you the actual number of atoms of each element in a molecule, while the empirical formula represents the simplest whole number ratio of these atoms.
Question: How can you deduce the empirical formula from the molecular formula?
Answer: From the molecular formula, the empirical formula can be deduced by finding the simplest whole number ratio of atoms of each element.
Can the empirical formula and molecular formula be the same?
Answer: Yes, sometimes the empirical formula and molecular formula are the same, such as in the case of CO2
Question: How can you determine the empirical formula of an ionic compound represented by a dot-and-cross diagram?
Answer: Count the number of atoms of each element in the diagram, as this is equal to the empirical formula of the compound
Question: What steps are involved in determining the empirical formula of an ionic compound represented by a 3D lattice structure?
Answer: Identify the ions in the lattice, write them down, and balance the charges so that the overall charge is zero. The resulting formula is the empirical formula of the compound
Question: How can you calculate the percentage by mass of an element in a compound?
Answer: The percentage by mass of an element in a compound can be calculated using the formula:
Ar x number of atoms of the element / Mr of compound x 100
Question: What is an alloy, and how does it differ from a pure metal?
Answer: An alloy is a mixture of metals, whereas a pure metal consists of a single metal element. Alloys are typically stronger and harder than pure metals due to the presence of atoms of different sizes, which disrupt the regular arrangement of atoms and prevent easy sliding of layers
What is a formulation, and what are some examples?
Answer: A formulation is a mixture designed as a useful product, typically made by following an exact recipe with carefully measured quantities of each component. Examples of formulations include paint, medicines, food, and alloys.
Question: Why are most metals mixed with other elements to form alloys?
Answer: Most metals are too soft to use on their own, so they are mixed with other elements to make them stronger and harder.
Question: How do alloys differ in structure from pure metals, and why are they typically harder?
Answer: Alloys contain atoms of different sizes, which disrupt the regular arrangement of atoms in pure metals. This distortion makes it more difficult for the layers of atoms to slide over each other, resulting in alloys that are usually much harder than pure metals.
Question: What is filtration, and when is it used in chemistry?
Answer: Filtration is a separation technique used to separate an undissolved solid from a mixture of the solid and a liquid or solution. It is commonly used, for example, to separate sand from a mixture of sand and water.
Question: Describe the process of filtration.
Answer: In filtration, a piece of filter paper is placed in a filter funnel above a beaker. The mixture of insoluble solid and liquid is poured into the filter funnel. The filter paper allows only small liquid particles to pass through as filtrate, while solid particles are too large to pass through and stay behind as a residue.
Question: What is crystallisation, and when is it used in chemistry?
Answer: Crystallisation is a separation technique used to separate a dissolved solid from a solution, particularly when the solid is much more soluble in hot solvent than in cold. It is commonly used, for example, to separate copper sulphate from a solution of copper (II) sulphate in water
Question: Describe the process of crystallisation.
Answer: In crystallisation, the solution is heated, allowing the solvent to evaporate, leaving behind a saturated solution. To test if the solution is saturated, a clean, dry, cold glass rod is dipped into the solution. If the solution is saturated, crystals will form on the glass rod. The saturated solution is then allowed to cool slowly, causing crystals to grow as solids come out of solution due to decreasing solubility. Finally, the crystals are collected by filtering the solution, washed with cold distilled water to remove impurities, and allowed to dry.
Question: What is simple distillation, and when is it used in chemistry?
Answer: Simple distillation is a separation technique used to separate a liquid and soluble solid from a solution, or to separate a pure liquid from a mixture of liquids. It is commonly used, for example, to separate water from a solution of saltwater.
Question: Describe the process of simple distillation.
Answer: In simple distillation, the solution is heated, causing the pure liquid (such as water) to evaporate and produce a vapor. This vapor rises through the neck of the round-bottomed flask and passes through a condenser, where it cools and condenses back into a pure liquid. The condensed liquid is collected in a separate container (usually a beaker). After all the liquid has evaporated from the solution, only the solid solute will be left behind in the flask
Question: What is fractional distillation, and when is it used in chemistry?
Answer: Fractional distillation is a separation technique used to separate two or more liquids that are miscible with one another, such as ethanol and water from a mixture of the two
Describe the process of fractional distillation
Answer: In fractional distillation, the solution is heated to the temperature of the substance with the lowest boiling point. This substance will rise and evaporate first, and its vapors pass through a condenser, where they cool and condense into a liquid collected in a beaker. The fractionating column contains glass beads, increasing the surface area for evaporation and condensation. This allows substances with higher boiling points to condense more readily, leaving substances with lower boiling points to evaporate out of the column and into the condenser. For example, in the fractional distillation of a mixture of ethanol and water, ethanol, with a lower boiling point, evaporates first and is collected before water, with a higher boiling point, begins to evaporate.
Question: When given a mixture, how do you determine which separation techniques to use?
Answer: To determine the appropriate separation techniques, consider the properties of the components in the mixture. Choose techniques that can effectively separate each component based on its solubility, size, or other characteristics.
Question: What is chromatography, and what is its purpose?
Answer: Chromatography is a technique used to separate substances and provide information to help identify them
Describe the process of paper chromatography.
Answer: In paper chromatography, a pencil line is drawn on chromatography paper, and spots of the sample are placed on it. The paper is then lowered into a solvent container, allowing the solvent to travel up the paper by capillary action. Different substances in the sample have different solubilities and adhesion to the paper, causing them to spread apart as they travel up the paper. Those with higher solubility travel further than others, based on their differing affinities for the mobile (solvent) and stationary (paper) phases.
What are the two phases involved in paper chromatography, and what are their roles?
Answer: In paper chromatography, the mobile phase is the solvent (liquid) in which the sample molecules move, while the stationary phase is the chromatography paper itself. The differing affinities of substances for these phases determine the speed at which they move through the paper.
Question: How does thin-layer chromatography (TLC) differ from paper chromatography?
Answer: Thin-layer chromatography (TLC) works similarly to paper chromatography but uses a different stationary phase. Instead of paper, TLC uses a thin layer of an inert substance (e.g., silica) supported on a flat, unreactive surface
Question: What is the stationary phase in thin-layer chromatography (TLC), and what is its purpose?
Answer: In thin-layer chromatography (TLC), the stationary phase is a thin layer of an inert substance (e.g., silica) supported on a flat, unreactive surface. It provides a surface for the separation of substances based on their interactions with the mobile phase.
Question: What is chromatography, and what is its purpose?
Answer: Chromatography is a technique used to separate substances and provide information to help identify them.
Question: What are the two phases involved in chromatography?
Answer: The two phases in chromatography are the mobile phase and the stationary phase.
Question: What is the mobile phase in paper chromatography?
Answer: In paper chromatography, the mobile phase is the solvent in which the sample molecules can move, such as water or ethanol.
Question: How does paper chromatography work, and what are the key steps involved?
Answer: In paper chromatography, a pencil line is drawn on chromatography paper, and spots of the sample are placed on it. The paper is then lowered into a solvent container, allowing the solvent to travel up the paper by capillary action. Different substances in the sample have different solubilities and adhesion to the paper, causing them to spread apart as they travel up the paper. Substances with higher solubility travel further, as they spend more time in the mobile phase and are carried further up the paper.
Question: What are the two phases involved in chromatography?
Answer: The two phases in chromatography are the mobile phase and the stationary phase
Question: What is the mobile phase in paper chromatography?
Answer: In paper chromatography, the mobile phase is the solvent in which the sample molecules can move, such as water or ethanol
Question: What is the stationary phase in paper chromatography?
Answer: In paper chromatography, the stationary phase is the chromatography paper itself.
Question: How does thin-layer chromatography (TLC) differ from paper chromatography?
Answer: Thin-layer chromatography (TLC) works similarly to paper chromatography but has a different stationary phase.
Question: What is the stationary phase in thin-layer chromatography (TLC)?
Answer: In thin-layer chromatography (TLC), the stationary phase is a thin layer of an inert substance (e.g., silica) supported on a flat, unreactive surface.
Question: What is the mobile phase in thin-layer chromatography (TLC)?
Answer: In thin-layer chromatography (TLC), the mobile phase is a solvent, similar to paper chromatography
Question: What are Rf values used for in chromatography?
Answer: Rf values are used to identify the components of mixtures in chromatography.
How does the solvent used affect the Rf value?
Answer: The Rf value of a compound is dependent on the solvent used; changing the solvent changes the Rf value
Question: How is the Rf value calculated?
retention factor = distance moved by compound / distance moved by solvent
Question: How can chromatography be used to distinguish between pure substances and mixtures?
Answer: Pure substances will produce only one spot on the chromatogram, while mixtures will separate on the paper to show all the different components as separate spots.
Question: What does it indicate if a chromatogram has more than one spot?
Answer: An impure substance will produce a chromatogram with more than one spot, indicating the presence of multiple components or impurities in the sample
Question: What is gas chromatography used to separate?
Answer: Gas chromatography is used to separate a mixture of gases.
Question: What are the mobile and stationary phases in gas chromatography?
Answer: In gas chromatography, the mobile phase is an unreactive carrier gas (e.g., nitrogen), and the stationary phase is a thin layer of an unreactive liquid (e.g., silica or aluminium powder)
Question: Describe the process of gas chromatography.
Answer: In gas chromatography, the mixture sample is injected into the column, and the mixture is carried by the carrier gas through the column. Different substances in the mixture will take different times to travel through the column, known as retention time, due to their attraction to the stationary phase. Substances with more attraction to the stationary phase will take longer to move through the column. As each component leaves the column, a peak is plotted against the travel time on a chromatogram generated by a computer.