2. Redox Flashcards

1
Q

what is oxidation

A

loss of e-

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2
Q

what happens to the oxidation #/state when oxidation happens

A

increases

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3
Q

what does an oxidant cause

A

oxidation

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4
Q

what happens to an oxidising agent

A

it gets reduced

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5
Q

what happens in reduction

A

gain e-

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6
Q

what happens to the oxidation #/state in reduction

A

decreases

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7
Q

what does a reductant cause

A

reduction

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8
Q

what happens to the reducing agent

A

gets oxidised

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9
Q

what is the oxidation # of elements

A

0

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10
Q

what is the oxidation # of atom in monoatomic ion

A

charge on ion

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11
Q

what is the oxidation # of O2 in compound

A

-2

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12
Q

what is the oxidation # of O2 in peroxides

A

-1

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13
Q

what is the oxidation # of H in compound

A

+1

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14
Q

what is the oxidation # of H in metal hydrides

A

-1

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15
Q

what is the sum of oxidation # of atoms in a molecule

A

0

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16
Q

what is the sum of oxidation # of atoms in a polyatomic ion

A

charge on ion

17
Q

how to balance equations

A

add H20 to balance Os

add H+ to balance Hs

add e- to balance charge

18
Q

what is an electrode

A

electricity conductor

reactions occur on their surface

19
Q

what is an anode - what occurs here

A

oxidation occur at this electrode

20
Q

what is a cathode - what occurs here

A

reduction occur at this electrode

21
Q

what are anions and where do they move towards

A

-

move towards anode

22
Q

what are cation and where do they move towards

A

+

move towards cathode

23
Q

how does a galvanic electrochemical cell work

A

2 half cells connected via

int circuit = ions through electrolyte to maintain charge

ext circuit = e- move through wire between electrodes

causes electric current to flow via 2 different metals resulting in e- transfer

24
Q

how does an electrolytic cell work

A

electrolysis where power supply forces oxidation and reduction via e- movement in ext circuit

electrolyte allows ion movement = int circuit

25
Q

if the standard reduction potential is further up what does this mean

A

more easily reduced

stronger oxidant

26
Q

if the overall E* is + what does this mean

A

spontaneous

27
Q

when calculating E* cells for oxidated species what must you do

A

flip + and negative signs for oxidised species