2. Quantum Phenomena Flashcards

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1
Q

If you shine light of a high enough _______ onto the surface of a metal, it will emit electrons.

A

Frequency

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2
Q

What is the photoelectric effect?

A

When electrons on the surface of a metal absorb enough energy from light to overcome bonds holding it to the metal, allowing it to be released.

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3
Q

Define threshold frequency.

A

Minimum frequency required for electrons to be released from the surface of a metal.

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4
Q

Does intensity of the radiation affect the maximum kinetic energy a electron has.

A

No, frequency does.

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5
Q

The number of photo-electrons emitted per second is proportional to what?

A

the intensity of the radiation.

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6
Q

What are the discrete packets of electromangentic waves Einstein suggested?

A

Photons

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7
Q

What is the h in the equation: E = hf?

A

Planck’s constant

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8
Q

A photon would transfer all its _____ to one specific electron.

A

energy.

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9
Q

If one photon collides with a free electron, the energy the electrons will gain is equal to ____

A

hf

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10
Q

Define work function.

A

The minimum amount of energy required to break the bonds holding the electrons to the atom and allow it to flee the metals surface.

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11
Q

If the energy delivered by the photon is below the work function, what happens?

A

No electron emission

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12
Q

What is the equations for threshold frequency?

A

frequency = work function/ planck’s constant

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13
Q

What is the maximum kinetic energy equal to?

A

hf - work function

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14
Q

is the kinetic energy dependent on the intensity of the radiation?

A

No as each electron only absorbs one photon at a time. Increasing the intensity just means more photons per second on an area, each photons have the same energy as before.

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15
Q

Define stopping potential.

A

It is the p.d needed to stop the fastest moving electron.

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16
Q

In an atom, where do the electrons exist?

A

In well-defined energy shells.

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17
Q

How can electrons move down energy levels?

A

By emitting photons.

18
Q

The energy of each photon either emitted or absorbed must be equal to what?

A

Energy needed for the electron to transition to a different energy shell.

19
Q

How many joules are there in a electronvolt?

A

1.60 x 10^-19J

20
Q

Define the electronvolt.

A

The kinetic energy carried by an electron after it has been accelerated through a potential difference of 1V.

21
Q

Define excitation.

A

Movement of an electron to a higher energy level. This is done by the electron absorbing an photon which carries an amount of energy equal to the energy difference between the two energy shells.

22
Q

What does it mean if an atom becomes ionised?

A

An electron is removed from the atom, making the atom positively ionised.

23
Q

Define ionisation energy.

A

Amount of energy required to completely remove an electron from an electron from the atom from the ground state.

24
Q

What is the ground state?

A

Lowest energy level, nearest the nucleus.

25
Q

How is light produced in a fluorescent tube?

A

Free electrons collide with electrons in mercury atoms, causing them to excite to higher energy levels. These electrons then return to their original energy levels, releasing a UV photon. The phosphorus coating on the tube absorbs photons, exciting electrons to much higher orbits. These electrons cascade down the levels, emitting visible light photons.

26
Q

How is a light spectrum formed?

A

Light from fluorescent tubes hits prism or diffraction grating, creating a line spectrum.

27
Q

What is a light spectrum?

A

Series of bright lines against a black background. Each line corresponds to a particular wavelength of light emitted by the source.

28
Q

Why is white light described as continuous?

A

Contains all possible wavelengths. The colours all merge into each other - there is no gaps in the spectrum.

29
Q

Does hot or cold things emit a continuous spectrum in the visible and infrared?

A

Hot things.

30
Q

Are electrons confined to energy levels in objects producing a continuous spectrum?

A

No, electrons are not bound to the atom and are free.

31
Q

You get _____________ when light with a continuous spectrum of energy passes through a cool gas.

A

Line spectrum.

32
Q

At low temperature, most of the electrons in the gas atoms will be in their ________________.

A

Ground state.

33
Q

Why are certain wavelengths missing in a continuous spectrum when it comes out the other end of a cool gas.

A

The electrons absorb photons with a specific energies equal to the difference between two energy levels. Photons of the corresponding wavelength cause excitation of electrons. These wavelengths are missing from the continuous spectrum.

34
Q

Why is finding the line spectra useful?

A

Each element has its own unique line spectra like a barcode and so the element can be identified using this.

35
Q

___________ and ____________ show light as a wave.

A

Interference and diffraction.

36
Q

_____________ ________ shows light behaving as a particle.

A

Photoelectric Effect

37
Q

What was De Broglie Suggestion?

A

If wave-like light showed particle properties (photons), particles like electrons should be expected to show wave-like properties.

38
Q

What is the ‘mv’ in the de Broglie equation?

A

Mass x velocity which is the momentum.

39
Q

What observation can be used to show that electrons have a wave like nature.

A

Electron diffraction. Diffraction patterns are observed when accelerated electrons in a vacuum tube interact with the spaces in a graphite crystal.

40
Q

____________ the electron speed and the diffraction pattern squashes together towards the middle. This supports the de Broglie equation.

A

Increase

41
Q

An electron with a ___________ mass, makes the diffraction pattern more closely packed.

A

Greater