2 - introduction to isotopes and what they are Flashcards
isotopes
atoms of the same element that vary in mass due to different number of neutrons
(horizontal)
isobar
atoms of different elements with different no. protons and neutrons but the same overall mass balance (diagonal?)
isotone
atoms of different elements, different protons and neutrons (vertical)
becoming neutron heavy means
increasing autonomic number (right of the line)
what elements are radioactive
most elements are not
only certain elements isotopes
253/288 natural isotopes so no evidence of radioactive decay
60% of natural isotopes have..
.. Even number of protons and/or neutrons
in general are the most abundant isotopes on earth
40% of natural isotopes have…
… even number of protons and odd number of neutrons
… odd number of protons and even number of neutrons
4 stable nuclei
odd number of protons and neutrons - all with relatively low numbers:
(2/1)H, (6/3)Li, (10/5)B, (14/7)N
elements with an ??? Z have more stable isotopes
EVEN
area of stability
plot A against Z for all known nuclei
Z/N ratio gradually ???? until element ??
decreases
83 (Bi, the last on with a stable isotope)
at high Z stability of a nuclide is favored by being …
… neutron rich
stability of a nuclide is favored by …
… even number of protons and neutrons but not usually equal numbers
coulombrepulsion
protons have positive charge so repel one another
as increasing number of protons, an excess of neutrons is required to over come the proton-proton repulsion
strong nuclear force
neutrons are neutral and produce attractive forces with nuclei
strong neutron force happens over a very short length scale, must be a lot closer than with Coulomb repulsion
the shell model
each nucleon is assumed to exist in a shell similar to atomic shells for electrons
the nucleons exist in quantized energy states
each state can contain only two protons or neutrons
- they must have opposite spins
- they must have spire of 1/2 therefore the exclusion principal applies
protons and neutrons occupy separate sets of energy sets
radio activity - Alpha (a) decay
involves a parent isotope (the radioactive isotope that goes under decay) to create the daughter/radiogenic isotope
loosed a particle - two protons, two neutrons - so both Z&N decry by 2
the decay scheme - down to left
alpha decay always has a slope of +1, from upper right to lower left
Radio activity - B decay
one of the neutrons is an outer energy unstable half energy state
parent loses a neutron (N down by 1) and the neutron is converted to a proton (Z increase by 1)
mass no. remains the same
Parent - daughter = isobars
decay scheme = up left (?)
Radio activity - electron capture
proton (from parent) dissociated/loses/ejects a proton
proton changes to a neutron
-1Z, +1N
potassium Aragon dating
down right decay scheme (?)
valley of stability
further away from central axis the slope gets steeper
stable elements at base of valley
electron capture, proton rich left hand side of the valley
1902 Rutherford and saddy
rate of decay of an unstable parent isotope is proportional to the number of atoms of the parent present at any time
-dN/dt proportional N
the proportionality can be replaced with a decay constant lamda, this constant lamda represents the probability that an atom will decay within a stated period of time
-dN/dt = lamda N
can also think of radioactive decay in terms of how long it takes for half the number of radioactive atoms present in a sample to decay
Half life can then be derived from the decay constant for any element using;
T1/2 = ln2/lamda = 0.69315/lamda
isochron equation
if the number of daughter atoms in a sample at a time zero is Do, then the total number of daughter atoms (D) after the decay of the unstable parent (N) after time t is given by:
D = Do + N (e (^lamda t) - 1)
IMPORTANT
is the fundamental basis of geochronological dating methods using radiogenic isotopes
D & N can be measured, Do determined
the equation can be solved for the age ‘t’ as long as the decay constant lamda or T1/2 fir the element in question is known
two basic assumptions made when using radioactive decay and isochron equation to date rocks
- the decay constant for the element is known
2. the decay constant for the element has not changed over time
methods for determining the decay constant of an unstable isotope
- direct counting g
- daughter isotope measurement
- geological comparison