2 Energetics and Enthalpy Changes Flashcards

0
Q

What is the definition for the standard enthalpy change?

A

The enthalpy change that happens when one mole of a substance is completely combusted in oxygen under standard conditions

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1
Q

What does effervescence mean?

A

Bubbles a lot

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2
Q

What is the symbol for the standard enthalpy change of combustion?

A

C

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3
Q

When working out standard enthalpy change what are the rules?

A

First must be one mole

Can halve diatomic molecules

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4
Q

What is the definition for the standard enthalpy change of formation?

A

The enthalpy change when one mole of a compound is formed from its elements in their standard states

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5
Q

Do elements have an enthalpy change for formation?

A

Nope

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6
Q

When working out enthalpy change, what form of carbon must be used?

A

Graphite

C(graphite)

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7
Q

What is the symbol for the standard enthalpy change of formation?

A

f

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8
Q

What is the definition for the standard enthalpy change of atomisation?

A

The enthalpy change when one mole of its atoms in the gaseous state is formed from the element under standard conditions

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9
Q

What is the symbol for standard enthalpy change of atomisation?

A

at

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10
Q

Standard enthalpy changes of atomisation is and exothermic/endothermic process

A

Exothermic

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11
Q

What doesn’t have a standard enthalpy change of atomisation?

A

Noble gases

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12
Q

What is the definition of the energy change of neutralisation?

A

The enthalpy change of a reaction where one mole of acid is neutralised by an alkali in their standard states at 298K and in solutions containing 1moldm(3)

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13
Q

What is the enthalpy of neutralisation for strong acids with strong bases?

A

-58kJmol

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14
Q

What is the definition of Hess’ Law?

A

The enthalpy change is independent of the path taken

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15
Q

What happens if you the opposite way in Hess’ Law?

A

You subtract the value of the enthalpy change

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16
Q

What is ALWAYS produced as a result of combustion?

A

Carbon dioxide

Water

17
Q

What is the equation for energy change?

A

Mass (g) x specific heat capacity (JK[-1]g[-1]) x temperature change (K)

18
Q

What is the equation for working out standard enthalpy change?

A

Sum of bonds broken - sum of bonds made

Sum of enthalpy change of formation (products) - sum of enthalpy change of formation (reactants)

19
Q

What is the equation for the number of moles?

A

Mass in g/mass of 1 mile
Volume gas dm(3)/24dm(3)
Concentration x volume

20
Q

What does the term ‘enthalpy change of a reaction’ mean?

A

Heat energy that is released into the surroundings in an exothermic reaction

21
Q

What is the definition for lattice enthalpy?

A

Standard enthalpy change of formation of one mole of an ionic compound from its gaseous ions under standard conditions

22
Q

What is the definition for standard molar entropy change of atomisation?

A

The enthalpy change that takes place when one mole of gaseous atoms is formed from its elements in its standards state under standard conditions

23
Q

What is the definition of electron affinity?

A

Energy change when one mole of gaseous atoms acquire one mole of electrons to form a single negatively charged ion

24
What is energetics?
Study on energy transfers between reacting chemicals and surroundings
25
Does breaking bonds will require energy or release energy?
Require
26
Does making bonds require or release energy?
Release
27
Give an example of an exothermic reaction and an endothermic reaction
Exothermic – neutralisation | Endothermic – photosynthesis
28
What is the definition for enthalpy change of reaction?
Exothermic reaction releases energy to the surroundings in the form of heat
29
What is the system?
The reaction in which the changes are happening brackets products and reactants
30
What is meant by the surroundings?
Outside the system
31
What are the two sorts of boundaries and what do they prevent?
Closed prevents particles entering/leaving system | Isolated prevents particles and energy entering/leaving system
32
What is the first law of thermodynamics?
Energy cannot be created or destroyed
33
What happens to the energy transferred to surroundings?
Dissipated
34
What is the principle of conservation energy?
The total energy content of the universe is constant
35
What is the equation to work out the enthalpy change of a reaction
36
What is the enthalpy change of an exothermic reaction?
Negative H(products)< H(reactants) Net decrease in potential energy of the system
37
What is the enthalpy change of an endothermic reaction?
Positive H(products)> H(reactants) Net increase in potential energy of the system
38
What does the enthalpy level diagram of an exothermic reaction look like?
_______ | |______
39
What does the enthalpy level diagram of an endothermic reaction look like?
_____ | ____|
40
What is thermochemistry?
The study of the quantities of heat during reactions
41
What does enthalpy mean?
The energy content of the system held at constant pressure | Represented by H