2 - Combustion of alkanes Flashcards
Why are alkanes used as fuels?
They readily burn in the presence of oxygen and release heat energy when burnt
In excess oxygen alkanes will undergo…
complete combustion
What are the products of complete combustion?
- CO2 (g)
- H2O (l)
In limited amounts of oxygen alkanes will undergo…
incomplete combustion
What are the products of incomplete combustion?
- CO (g) OR C (s)
- H2O (l)
What pollutants are produced by internal combustion engines?
- Nitrogen oxides
- Carbon monoxide
- Carbon
- Unburned hydrocarbons
What is the environmental consequence of nitrogen oxides?
- NO is toxic and can form acidic gas NO2
- NO2 is toxic and acidic and forms acid rain
What is the environmental consequences of carbon monoxide?
Carbon monoxide is a toxic gas that binds to haemoglobin, preventing the binding of oxygen
What is the environmental consequence of carbon dioxide?
Contributes to global warming
What is the environmental consequence of unburnt hydrocarbons?
Contributes towards to formation of smog
What is the environmental consequence of soot (C)?
Global dimming and respiratory problems
What do catalytic converters do?
They remove CO, NOx and unburned hydrocarbons from exhaust gases by turning them into ‘harmless’ CO2, N2 and H2O
Write the equation of when carbon monoxide and nitrogen oxide react together in a catalytic converter
2CO + 2NO → 2CO2 + N2
Catalytic converters have a ceramic honeycomb coated with a thin layer of catalyst metals. Why is a thin layer used?
- To reduce the amount of metals needed
- Allows for a larger surface area
What are the 3 metal catalysts used in a catalytic converter?
- Platinum
- Palladium
- Rhodium
Combustions of hydrocarbons containing sulfur leads to the production of…
sulfur dioxide
How can sulfur dioxide cause air pollution?
Sulfur dioxide will dissolve in atmospheric water and can produce acid rain
Gases given out by power stations are called flue gases which contain sulfur dioxide. How can this be removed?
Through a process called flue gas desulfurisation
- A slurry of either calcium oxide or calcium carbonate with water is sprayed into the flue gases
- Flue gas reacts with the slurry and forms calcium sulfite
- This can be further oxidised to calcium sulfate