2 Chemistry Flashcards

1
Q

6 diff atoms of Orgo chem that are linked by covalent bonds

A
C
H
O
N
P
S
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2
Q

Covalent bond

A

Electrons shared by two atoms

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3
Q

Delocalization means what and what does it do

A

Sharing electrons, sharing electrons lowers the energy

Lower energy = increased stability = increased bond strength

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4
Q

Valence

Electronegativity

Geometry

A

Number of bonds, determines the structures that can form

Attracting electrons

Bond angels, determines the shape

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5
Q

Rank electronegativity

A
O attract e- strongly, shorter bonds
N
S
C
H
P
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6
Q

Polar vs non polar

A

Unequal charge distribution

No polar is the equal sharing, no pull

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7
Q

Tetrahedral

A

4 bonds

All paired 109.5
One lone pair 107
Two lone pairs 105 BENT

Double bond 120

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8
Q

Single vs double bonds

A

Single can rotate freely around bond, zigzag structure

Double cannot rotate freely, flat and rigid structure

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9
Q

Acid vs base

A

Acid is H+ donor

Base is H+ accepter

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10
Q

Instantaneous reactions

A

When bonds between H+ and non bonded e- pairs in N and O form/break very spontaneously

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11
Q

Resonance

A

Sharing electrons between 3 or more atoms

Increased resonance = increased stability

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12
Q

Energy yielded from atp hydrolysis comes from what

A

The additional resonance stabilization of ADP that is formed

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13
Q

Covalent vs non covalent

A

Covalent
Strong
Share electrons
Stable

Non covalent
Weaker
Non stable, break easily
Determine shape
Determine how molecules interact with each other
Large structures are held together by these bonds

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14
Q

Non covalent bond order

A

H bond
Electrostatic
Hydrophobic

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15
Q

Electrostatic aka

A

Ionic bond

Strength depends solely on distance

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16
Q

Hydrogen bond

A

Strength depends on distance and orientation

17
Q

Hydrophobic bond

A

Solvent effect in water
Water pushes non polar molecules together because they prefer to associate with other water molecules

Strength depends on h bonds between water

18
Q

Non polar surfaces attract each other

A

FALSEEEE they are pushed together by the solvent aka water

19
Q

As neutral atoms move closer together,

A

Repulsion decreases and attraction between nuclei increases

20
Q

Covalent
Non covalent
Hydrophobic

Van deer walls

A

Covalent 50 holds atoms together in molecules

Non 5 holds molecules together

Van .5 determines the packing of atoms in folded structures and large molecular assemblies