2 Chemistry Flashcards
6 diff atoms of Orgo chem that are linked by covalent bonds
C H O N P S
Covalent bond
Electrons shared by two atoms
Delocalization means what and what does it do
Sharing electrons, sharing electrons lowers the energy
Lower energy = increased stability = increased bond strength
Valence
Electronegativity
Geometry
Number of bonds, determines the structures that can form
Attracting electrons
Bond angels, determines the shape
Rank electronegativity
O attract e- strongly, shorter bonds N S C H P
Polar vs non polar
Unequal charge distribution
No polar is the equal sharing, no pull
Tetrahedral
4 bonds
All paired 109.5
One lone pair 107
Two lone pairs 105 BENT
Double bond 120
Single vs double bonds
Single can rotate freely around bond, zigzag structure
Double cannot rotate freely, flat and rigid structure
Acid vs base
Acid is H+ donor
Base is H+ accepter
Instantaneous reactions
When bonds between H+ and non bonded e- pairs in N and O form/break very spontaneously
Resonance
Sharing electrons between 3 or more atoms
Increased resonance = increased stability
Energy yielded from atp hydrolysis comes from what
The additional resonance stabilization of ADP that is formed
Covalent vs non covalent
Covalent
Strong
Share electrons
Stable
Non covalent
Weaker
Non stable, break easily
Determine shape
Determine how molecules interact with each other
Large structures are held together by these bonds
Non covalent bond order
H bond
Electrostatic
Hydrophobic
Electrostatic aka
Ionic bond
Strength depends solely on distance