2. Atomic structure Flashcards

1
Q

number of protons in an atom=

A

number of electrons

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2
Q

isotopes are different atoms of the same element with different

A

mass numbers (neutrons)

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3
Q

isotopes have the same … properties but different … properties

A

same chemical
different physical

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4
Q

relative atomic mass Ar is the

A

average of the masses of the isotopes in a naturally occurring sample of the element relative to the mass of 1 of an atom of carbon-12

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5
Q

electrons fill the … energy levels first

A

lower

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6
Q

in emission spectrum, lines converrge at

A

high frequency / high energy

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7
Q

how is the emission spectrum formed?

A
  1. with the help of an electric discharge, electron is promoted to a higher energy level
  2. electron is unstable and will fall to a lower energy level
  3. energy is given out in the form of light
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8
Q

aufbau principle

A

electrons fill sub-levels from the lowest energy level upwards – this gives the lowest possible (potential) energy

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9
Q

the 4s sub-level is lower in energy than the

A

3d sub-level

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10
Q

an orbital is a region of space where

A

there is a high probability of finding an electron
represents a discrete energy level

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11
Q

an orbital contains maximum … electrons

A

2

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12
Q

orbitals with same energy

A

degenerate

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13
Q

pauli exclusion principle

A

opposite spin

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14
Q

hund’s rule

A

electrons fill degenerate orbitals. so as to give the max number of electrons with the same spin

→ this is why we have arrows going in the same direction

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15
Q

ionisation energy

A

the minimum amount of energy required to remove an electron from a gaseous atom

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16
Q

E =

A

hv = hc/λ

17
Q

first ionisation energy

A

energy required to remove one electron from. each atom in one mole of gaseous atoms under standard conditions

18
Q

ionisation energy … across a period

A

increases
increase in effective nuclear charge felt by outer electron

19
Q

exceptions to the trend in ionisation energy across a period:

A

boron ionisation energy is lower than beryllium
→ 2p sub-level is higher in B, therefore easier to remove than from Be

first IE of oxygen is lower than for nitrogen

20
Q

in transition metals, 4s electrons are always removed before the

A

3d
even if sub levels are filled in order 4s the 3d