1st and 2nd laws Flashcards

1
Q

0th law of thermodynamics

A

If T3=T2 and T1=T3,
then T1=T2

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2
Q

Open system

A

Exchange of matter and energy with the surrounding

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3
Q

Closed system

A

Exchange of energy only with the surrounding

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4
Q

Isolated system

A

No exchange of matter and energy with the surrounding.
(No surrounding)

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5
Q

Q

A

heat

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6
Q

W

A

work

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7
Q

U

A

internal energy

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8
Q

1st law of thermodynamics

A

ΔU = Q + W

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9
Q

ΔU is +

A

if temperature T increases

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10
Q

ΔU is -

A

if temperature T decreases

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11
Q

ΔU is 0

A

if temperature T is constant

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12
Q

Q is +

A

if heat enters system

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13
Q

Q is -

A

if heat exists system

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14
Q

Q is 0

A

if no heat exchange

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15
Q

W is +

A

if work is done on the system

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16
Q

W is -

A

if work is done by the system

17
Q

W is 0

A

if volume is constant

18
Q

Adiabatic system

A

No exchange of matter and energy with the surrounding.
(can do/have work done)

19
Q

Isochoric

A

Closed system at constant volume

20
Q

Isobaric

A

Closed system at constant pressure

21
Q

Intensive property

A

Independent of the size of the system
(e.g. P, T)

22
Q

Extensive property

A

Scale linearly with the size of the system
(e.g. V, n)

23
Q

1 N (force)

A

1 kg.m/s²

24
Q

1 J (work)

A

1 N.m
1 kg.m²/s

25
Q

1 Pa (pressure)

A

1 N/m²
1 kg/m.s²

26
Q

Isothermal

A

Constant temperature in system
(Heat transfer between system and surrounding)

27
Q

Reversible

A

Infinitely small change to the system

28
Q

Entropy (S)

A

measure of available microstates of the system
= J/K
= kg.m²/s².K⁻¹

29
Q

Enthalpy (H)

A

H = U + P.V

30
Q

Work on system (eq)

A

W = -M.g.Ah/A
= -Pext .ΔV

31
Q

R constant

A

8,314 J/(K.mol)

32
Q

State function

A

do not depend on path (U, H, A, G)

33
Q

Path function

A

depend on path (Work, heat)

34
Q

Helmotz energy (A)

A

A = U - T.S

35
Q

Gibbs energy (G)

A

G = U + P.V - T.S

36
Q

heat

A

energy transfer (act of transfer)

37
Q

heat capacity

A

change in internal energy

38
Q

Exothermic reaction

A

releases energy (cold feeling)

39
Q

Endothermic reaction

A

absorbs energy (hot feeling)