1st and 2nd laws Flashcards

1
Q

0th law of thermodynamics

A

If T3=T2 and T1=T3,
then T1=T2

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2
Q

Open system

A

Exchange of matter and energy with the surrounding

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3
Q

Closed system

A

Exchange of energy only with the surrounding

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4
Q

Isolated system

A

No exchange of matter and energy with the surrounding.
(No surrounding)

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5
Q

Q

A

heat

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6
Q

W

A

work

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7
Q

U

A

internal energy

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8
Q

1st law of thermodynamics

A

ΔU = Q + W

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9
Q

ΔU is +

A

if temperature T increases

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10
Q

ΔU is -

A

if temperature T decreases

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11
Q

ΔU is 0

A

if temperature T is constant

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12
Q

Q is +

A

if heat enters system

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13
Q

Q is -

A

if heat exists system

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14
Q

Q is 0

A

if no heat exchange

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15
Q

W is +

A

if work is done on the system

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16
Q

W is -

A

if work is done by the system

17
Q

W is 0

A

if volume is constant

18
Q

Adiabatic system

A

No exchange of matter and energy with the surrounding.
(can do/have work done)

19
Q

Isochoric

A

Closed system at constant volume

20
Q

Isobaric

A

Closed system at constant pressure

21
Q

Intensive property

A

Independent of the size of the system
(e.g. P, T)

22
Q

Extensive property

A

Scale linearly with the size of the system
(e.g. V, n)

23
Q

1 N (force)

A

1 kg.m/s²

24
Q

1 J (work)

A

1 N.m
1 kg.m²/s

25
1 Pa (pressure)
1 N/m² 1 kg/m.s²
26
Isothermal
Constant temperature in system (Heat transfer between system and surrounding)
27
Reversible
Infinitely small change to the system
28
Entropy (S)
measure of available microstates of the system = J/K = kg.m²/s².K⁻¹
29
Enthalpy (H)
H = U + P.V
30
Work on system (eq)
W = -M.g.Ah/A = -Pext .ΔV
31
R constant
8,314 J/(K.mol)
32
State function
do not depend on path (U, H, A, G)
33
Path function
depend on path (Work, heat)
34
Helmotz energy (A)
A = U - T.S
35
Gibbs energy (G)
G = U + P.V - T.S
36
heat
energy transfer (act of transfer)
37
heat capacity
change in internal energy
38
Exothermic reaction
releases energy (cold feeling)
39
Endothermic reaction
absorbs energy (hot feeling)