1a- Electromagnetic radiation and atomic spectra Flashcards

1
Q

What can electromagnetic radiation be characterised in terms of?

A

Wavelength and/or frequency

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2
Q

The different types of radiation arranged in order of wavelength is known as what?

A

The electromagnetic spectrum

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3
Q

In what unit are wavelengths of visible light usually expressed?

A

nanometres (nm)

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4
Q

Why is electromagnetic radiation said to have a dual nature?

A

Because it can be described as both a wave (has a wavelength and a frequency) and as a particle

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5
Q

When electromagnetic radiation is absorbed or emitted by matter how does it behave?

A

It behaves like a stream of particles. These particles are known as photons

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5
Q

A photon carries quantised energy proportional to what?

A

The frequency of the radiation

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6
Q

When a photon is absorbed or emitted, what happens to the electrons within the substance?

A

Energy is either gained or lost by the electrons

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7
Q

Photons in which type of radiation can transfer greater amounts of energy?

A

High frequency radiation

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8
Q

In what units is energy usually expressed?

A

kJ/mol

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9
Q

What happens to the electrons within atoms when energy is transferred to them?

A

The electrons may be promoted to higher energy levels

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10
Q

When does an atom emit a photon of light energy?

A

When an excited electron moves from a higher to a lower energy level

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11
Q

What does the light energy emitted by an atom produce?

A

A spectrum that is made up of a series of lines at discrete (quantised) energy levels.

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12
Q

What does the spectrum produced when light energy is emitted by an atom provide direct evidence of?

A

The existence of energy levels

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13
Q

Each element in a sample produces characteristic absorption and emission spectra, what can these spectra be used for?

A

To identify and quantify the element

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14
Q

What happens during absorption spectroscopy?

A

Electromagnetic radiation is directed at an atomised sample. Radiation is absorbed as electrons are promoted to higher energy levels

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15
Q

An absorption spectrum is produced by measuring what?

A

How the intensity of absorbed light varies with wavelength

16
Q

What happens during emission spectroscopy?

A

High temperatures are used to excite electrons within atoms. As the electrons drop to lower energy levels, photons are emitted.

17
Q

An emission spectrum of a sample is produced by measuring what?

A

The intensity of light emitted at different wavelengths

18
Q

In atomic spectroscopy, the concentration of an element within a sample is related to what?

A

The intensity of light emitted or absorbed