1.9 Rate Equations Flashcards

1
Q

Define the term rate of reaction.

A

Change in concentration (of any reactant or product) per unit time. State what is being monitored (usually production of a product).

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2
Q

At a given instant, how could you calculate the rate of reaction?

A

Rate of reaction = change in concentration/ change in time

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3
Q

How could you measure the rate of reaction experimentally (different methods) ?

A

Use a colorimeter at suitable intervals if there is a colour change. If gas in evolved, use a gas syringe to collect volume of gas evolved, or measure the change in mass of the reaction.

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4
Q

How would you measure reaction rate for really fast reaction?

A

Use a flash of light to break bonds, use probe flashes to record amount of light absorbed by a species; this can show its concentration. First used for ClO2 ->ClO.+O.
Can now monitor reactions that occur in times as fast as 10-12 seconds.

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5
Q

How can you determine the rate constant and rate expression for a reaction?

A

Only experimentally

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6
Q

What affects the value of the rate constant for a given reaction?

A

Temperature, nothing else.

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7
Q

Write a generic rate expression and state what each term means.

A

Rate = k [X]^x [Y]^y;
k = rate constant for the reaction
[X] and [Y] are concentrations of species X and Y respectively x and y are the orders of reaction with respect
to X and Y.

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8
Q

Do species need to be in the chemical equation to be in the rate expression?

A

No - species sin the chemical equation may be excluded and species not in the chemical equations e.g. catalysts, may be included.

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9
Q

Define the term order of a reaction with respect to a given product.

A

The power to which species’ concentration is raised in the rate equation.

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10
Q

Define the term overall order of reaction

A

The sum of the orders of reaction of all species in the rate expression e.g. (from earlier), total order = x + y

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11
Q

How would you calculate the units of the rate constant?

A

Units of rate are moldm^-3 s^-1 and units of concentration are mold dm^-3
Rearrange rate equation to get k=
sub in units and cancel them out.

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12
Q

How would you draw a rate concentration graph?

A

Plot [A] against time, draw tangents at different values -> draw a secondary graph of rate against [A].

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13
Q

Draw a rate concentration graph for zero order reactant.

A

In a zero order reaction the reactant has no effect on the rate of reaction. This means that as the concentration changes, the rate stays the same. A graph of rate of reaction against concentration is therefore a straight, horizontal line.

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14
Q

Draw a rate concentration graph for a first order reactant

A

In a first order reaction the reaction rate is proportional to the concentration of the reactant. So a graph of rate of reaction against concentration is a straight line with a positive gradient

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15
Q

Draw a rate concentration graph from a second order reactant.

A

For a second-order reaction, a plot of the inverse of the concentration of a reactant versus time is a straight line with a slope of k.

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16
Q

How could you find the rate expression using the initial rate method?

A

Do a series of experiments, during which you vary concentrations, so the concentration of just one reactant changes each time.
Plot a graph of concentration against time for each reactant and use a tangent at t=0 to find the initial rate of reaction.
Compare rates and concentrations between each experiment to find order of reactants and overall rate equation

17
Q

What must you add to react with the I2 as it is produced for an iodine clock reaction? (equation)

A

Known moles of sodium thiosulfate and a little starch; Reacts with I2 in 1:2 ratio
I2+2S2O3^2- –> S4O6^2- + 2I^-

18
Q

When does the starch turn a blue-black colour in an iodine clock reaction and why?

A

When all of the Na2S203 has been used up and so I2 is produced, which reacts with starch, leading to a blue black colour.

19
Q

How can you calculate the rate of reaction from the data from an iodine clock reaction?

A

Record time taken for colour change to occur.
Use rate = 1/t. This is effectively the initial rate.

20
Q

What is the effect of a 10K temperature increase on the rate of reaction, roughly?

A

Doubles rate of reaction.

21
Q

What is true of the half life of a first order reactant (concentration against time graph)?

A

Half life is constant.

22
Q

What is the Arrhenius equation? What does each term mean?

A

k= Ae -Ea/RT
k = rate constant for reaction
A = pre-exponential factor (number of collisions between reactant molecules)
e = mathematical quantity
R = gas constant
T = temperature in kelvin
Ea = activation energy for reaction in joules

23
Q

How can you convert the Arrhenius equation into a useful form for plotting a graph?

A

In k = -Ea/RT + In A

Graph of ink against 1/T us a straight line; gradient = -Ea/R and y intercept is InA.

24
Q

What is the rate determining step?

A

The slowest step in a reaction mechanism, which determines the overall rate of reaction.

25
Q

How does the rate determining step link to the species involved in the rate expression?

A

Any species involved in the rate determining step may appear in the rate expression. Species only involved after the rate determining step do not appear in the rate expression.