17 - 4 Flashcards

0
Q

How is rxn rate measured?

A

TRIANGLE [reactant]/unit time

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1
Q

What is rxn rate?

A

How fast a reaction happens

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2
Q

How can rxn rate be determined?

A

Experiment

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3
Q

What is one thing rxn rate determines?

A

How fast a cake bakes

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4
Q

What influences rxn rate?

A

Nature of the reactions & surface area, T, [. ], & catalyst

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5
Q

Define nature of the reactants

A

Ionic(reacts instantly) or covalent (May take hours)

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6
Q

Describe what happens when T increases

A

Increased T will increase KE which will increase the # of particles with enough energy to “go” WRT E-act

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7
Q

Describe what happens when [ ] increases

A

Will increase KE cuz there are more particles preset to collide

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8
Q

Define catalysts

A

Substances that increase the rate of a rxn without being involved in rxn

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9
Q

How do catalysts work?

A

By decreasing e-Act

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10
Q

When will a catalyst be homogenous?

A

WRT reactants (of the same phase)

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11
Q

When will catalysts be heterogeneous?

A

WRT reactants (different phases)

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12
Q

What’s the opposite of a catalyst?

A

Inhibitor

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13
Q

What is an inhibitor also known as?

A

Preservative

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14
Q

Define preservative

A

Stops or slows a rxn by forming stable, nonreactive intermediate species w/ reactants, keeping to busy to react

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15
Q

Define rate laws

A

Mathematical expressions that relate the rate of a rxn to the [ ]’s of thee reactants

16
Q

How do you write a rate law?

A
  1. ) Keep [ ] of reactants constant & time it
  2. ) vary the [ ] of one & time it again
  3. ) vary the [ ] of the other & time it again
17
Q

When is rxn rate 1st order?

A

Double-double

Triple-triple

18
Q

When is rxn rate 2nd order?

A

Double-quadruple

Triple- 9 fold