16.3 rate reactions Flashcards
what is the effect of concentration on zero order?
no effect
what is the effect of concentration on first order?
rate of reaction is directly proportional
what is the effect of concentration on second order?
rate of reaction is proportional to concentration squared
what are the 4 assumptions in a initial-rate (iodine-clock) experiment?
1- constant temperature
2- [reactants] doesn’t change significantly
3- reaction not proceeded too far when end point is seen
4- rate of reaction remains constant
how are different times taken recorded in reaction?
varying [I2] & [H2O2]
why is a starch indicator used in the iodine-clock experiment?
when S2O3 2- is used up, I2 reacts with starch & produces blue-black colour
what is the half-life?
time taken for 1/2 reactant to be used up
what is the respective changes in half-life for 0, 1st and 2nd orders?
0- half-life decreases
1- half-life constant
2- half-life increases