1.4 Flashcards
true or false: gas particle will move in a straight line until it collides with another particle thus changing direction (random movement); (Newton’s first law)
true
What does the ideal gas model(it is limited) assume?
- must be at room temperature
- at sea level
- particles in constant, random, straight line motion
- collisions are elastic (total KE constant); meaning the gas particles are not losing energy as a sample
- particles are tiny points with mass but no volume and far apart (meaning mostly empty space; volume negligible)
- no attractions/ repulsions between particles or for walls of containers (assume gas particles do not clump together); in reality all particles experience an electrostatic force of attraction
What is the most ideal gas?
Helium (He)
What are the non ideal gas conditions?
- low temperature
- high pressure
- particle size significant compared to space between particles
- interactions between particles are significant
Can the behavior of gases be predicted for non ideal gas conditions, and can the ideal gas law equation still be used?
No for both
What are real gases?
- molecules have REAL VOLUME (not points of mass)
-molecules are attracted to others by intermolecular forces
(volume & attraction)
true or false: for the ideal gas law does PV/RT = 1
true
Why how do the non ideal conditions for real gases deviate from the ideal gas law?
Conditions: low T and High P thus
-Attractions: as the particle collides with the wall of the container; if there are other neighbors around the particles as it collides with the wall, it will experience attraction backwards( in reality the pressure would be a lot less than the ideal gas law would predict)
-At very high pressure: We find that free space is actually a lot less than measured volume ( when we think of the volume of the gas sample, we are measuring the inside of the container assuming most is EMPTY SPACE)
Which equation must be used rather than the ideal gas law, and why?
The van der waals equation
- this is because it takes these factors that real gases exhibit into account (volume and attraction)
true or false; as the T increases, gases will return back to ideal gas behavior?
true