13.1 Oxygen and Sulfur Dioxide - Sulfur Dioxide Flashcards

WSET Issue 1.1 2020

1
Q

Name the 2 main functions of SO2.

A
  1. Anti-oxidant
  2. Anti-microbial
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2
Q

How does SO2 act as an antioxidant?

A
  • SO2 only reacts with oxygen itself very slowly
  • Reacts with the PRODUCTS (e.g., oxidative enzymes) of oxidative reactions
  • These products cannot oxidize further compounds in the wines
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3
Q

How does SO2 act as an anti-microbial?

A
  • Inhibits development of microbes (yeast and bacteria)
  • Different species vary in SO2 tolerance
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4
Q

In what state is SO2 applied?

A

Gas, solid or liquid.

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5
Q

Name 3 chemical forms of SO2.

A
  1. Sulfur dioxide
  2. Metabisulfite
  3. Potassium bisulfite
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6
Q

Does SO2 occur naturally? In the context of wine, how does it occur? What amount are produced?

A

Small amounts (10 mg/L) naturally produced during fermentation

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7
Q

What are the maximum allowable levels of SO2?

A
  • 160 mg/L for red, 210 mg/K white
  • Sweet wines permitted higher levels
  • Organic wines – lower levels
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8
Q

Is SO2 a toxic substance?

A

Yes. Its use is determined by local law.

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9
Q

What can So2 cause in some people?

A

Allergic reactions

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10
Q

If a bottle of wine contains more than 10 mg/L of SO2, what must happen?

A

“Contains Sulfites” must be printed on the label.

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11
Q

Do natural wine producers use SO2?

A

Usually no, but may in tiny amounts.

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12
Q

Is SO2 found in organic wines in the US?

A

No. SO2 use in organic wines is forbidden in the US.

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13
Q

At what points in the winemaking process is SO2 often used?

A

Larger amounts added at
1. Crushing
2. End of MLF
3. Bottling

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14
Q

Is it better to add SO2 throughout the winemaking process?

A

No. Adding it in small amounts at each step of the winemaking process is less effective than adding it in larger amounts at 3 stages: crushing, end of MLC and bottling.

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15
Q

What is “bound” SO2?

A

“Bound” SO2 reacts with compounds in the liquid

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16
Q

What is “free” SO2?

A

“Free” SO2 is not bound with compounds in the liquid.

17
Q

“Free” SO2 consists of what?

A
  1. Free SO2 - relatively inactive form
  2. Molecular SO2 - most effective against oxidation / microbes
18
Q

What is the largest component of free SO2?

A

Most of free SO2 is inactive. A small percentage of free SO2 consists of molecular SO2.

19
Q

Describe the 3 subcomponents of SO2.

A
  1. Bound SO2
  2. Free SO2
  3. Molecular SO2
20
Q

How does pH affect SO2 efficiency?

A

Lower pH = a greater proportion of free SO2 is in the molecular form.

21
Q

How do musts and wines with higher pH affect SO2 application?

A

Higher pH lowers the amount of molecular SO2. Therefore, wines need a greater amount of SO2 to be added in order to effectively protect them from microbes and oxidation.

22
Q

What happens to a wine if too much SO2 is added?

A

High levels:
1. Dull aromas / flavours
2. Makes wine harsh

23
Q

Name 4 ways to minimize use of SO2.

A
  1. Good winery hygiene
  2. Effective sorting
  3. Limiting oxygen exposure
  4. Cool temperatures