1.2 Carbohydrates Flashcards
The monomers from which larger carbohydrates are made.
Monosaccharides
3 common monosaccharides:
Glucose, galactose and fructose.
A condensation reaction between two monosaccharides forms…
a glycosidic bond.
Maltose is a disaccharide formed by condensation of…
two glucose molecules.
Sucrose is a disaccharide formed by condensation of…
a glucose molecule and a fructose molecule.
Lactose is a disaccharide formed by condensation of…
a glucose molecule and a galactose molecule.
The condensation of α-glucose produces…
the polysaccharides glycogen and starch.
The condensation of β-glucose produces…
the polysaccharide cellulose
Describe how the structure of starch is related to its function.
- Polysaccharide of α-glucose monomers. Glucose can be released to be used as a respiratory substrate (for example at night, when light dependent reaction of photosynthesis stops).
- Glucose monomers joined with 1-4 and 1-6 glycosidic bonds, so branched / coiled / (α-)helix, so makes molecule compact, so can fit many (molecules) in small volume.
- Mixture of amylose (helical and unbranched) and amylopectin (helical and branched). Amylose is more compact, amylopectin has more ends for hydrolytic enzyme action (to release glucose faster)
- Large molecule, so can’t cross the cell membrane AND is insoluble (in water), so doesn’t affect water potential
Describe how the structure of glycogen is related to its function.
- Helix/coiled/branched so compact;
- Polymer of glucose so easily hydrolysed;
- Branched / (1-4 and) 1-6 glycosidic bonds, so more ends for faster hydrolysis;
- Polymer of glucose (polymer) so provides respiratory substrate for energy release; [Nb glycogen releases glucose, not energy]
- Insoluble so not (easily) lost (from cell)
OR
Insoluble so does not affect water potential/osmosis;
Describe how the structure of cellulose is related to its function.
- Polymer of β-glucose joined by 1-4 glycosidic bonds;
- Alternate glucose monomers are upside down / rotated 180 degrees;
- Results in a long AND straight, unbranched polysaccharide [this is cellulose]
- Many cellulose molecules joined by hydrogen bonds to form microfibrils;
- Provide strength and inelasticity (to cell wall).
Which biochemical test indicates the presence of reducing sugars?
Benedict’s solution
Which biochemical test indicates the presence of starch?
Iodine/potassium iodide