1.2 Atomic Orbitals, Electronic Configurations and the Periodic Table Flashcards
Quanta
Fixed amount of energy of electrons in an atom
Principal Quantum Number (n)
Main energy level of an electron
Angular Momentum Quantum Number (l)
Shape of the subshell (s=0, p=1, d=2, f=3)
Magnetic Quantum Number (ml)
Orientation of orbital (between -l and +l)
Spin Magnetic Quantum Number
Direction of spin (+1/2 or -1/2)
Aufbau Principle
Electrons fill orbitals in order of increasing energy
Hund’s Rule
When degenerate orbitals are available, electrons fill each singly and with parallel spins before pairing up to fill orbitals
Pauli Exclusion Principle
No two electrons in one atom can have the same set of four quantum numbers
Isoelectronic
Particles which have the same electronic configuration
VSEPR (Valence Shell Electron Pair Repulsion) Theory
Used to predict the shapes of molecules and polyatomic ions
Calculating Electron Pairs
- Take total number of outer electrons of central atom and add one for every atom attached
- Add an electron for negative charge
- Remove an electron for positive charge
- Divide by two
Strength of Electron Pair Repulsions (strongest to weakest)
Non-bonding pair/non-bonding pair > non-bonding pair/bonding pair > bonding pair/bonding pair