10 - 14. ORGANIC CHEMISTRY Flashcards

1
Q

Why are substances insoluble

A

because there are no attractions that could occur between solvent and solute molecules that could outweigh the attractions between the solute atoms

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2
Q

Why does hydrolysis occur faster with OH ions that water

A

the negatively charged OH ion is a more effective nucleophile than the neutral water molecule

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3
Q

Where is the pair of electrons in a sigma bond found

A
  • between the nuclei of the two atoms sharing the electrons
  • the electrostatic attraction between the negatively charged electrons and the positively charged nuclei bonds the atoms to each other
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4
Q

What type of bond does the C=C double bond contain

A

sigma and pi bonds

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5
Q

Where is the pair of electrons in a pi bond found

A

above and below the plane of the atoms

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6
Q

Why are alkanes unreactive

A
  • the C-H bond is weakly polarised so they are not attacked by nucleophiles or electrophiels
  • there is no partial positive charge on a C atom to attract nucleophiles
  • they don’t have areas of high electron density to attract electrophiles
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7
Q

Why are alkenes reactive

A

they have pi bonding which is electron rich and attracts electrophiles

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8
Q

What are the effects of unburnt hydrocarbons on the environment

A
  • photochemical smog

- global dimming

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