#1- Thou Shalt Not Forget Flashcards
When reading measurements from a graduated instrument…
You must estimate by reading in between the graduated markings. This can give one more sig fig in your measurement
When ranking measuring devices from least to most precise
- Beaker(not for volume)
- Graduated cylinder
- Volumetric flasks (only one line)
- Serological pipette
- Burette
Density=Mass/Volume
When is it used?
Used in stoich to convert between mass and volume
The percent composition by mass for a pure compound…
Does not change. % must add up to 100
Percent yield=…
Experimental mass(Physical) /Theoretical mass(Calculated)
Percent error=…
|Experimental-Theoretical|/Theoretical
Mass spectrometry graphs depict…
The atomic masses and relative abundancies of isotopes
Isotopes of an element have the same number of ____, but have different numbers of ____, and therefore have a different _____ ______
Same PROTONS, different NEUTRONS, different MASS NUMBER
Empirical formula is…
Remembering Rhyme?
The simplest whole number ratio of moles(atoms) in the compound
Rhyme: Percent to mass, mass to mole(divide % by molar mass), divide by small, times until whole
Aufbau valence electron order:
(1s^2),(2s^2),(2p^6),(3s^2),(3p^6),(4p^2),(3d^10),(4p^6),(5s^2)
Electron configuration for cations(+ charge):
Remove the electrons from the outermost shells first. First p, than s, than d
When reading a PES graph, the higher the peak the ______ electrons there are in that sublevel
The MORE electrons there are in that sublevel
When reading a PES graph, a _____ binding energy means that the electrons are ______ to the nucleus
A LARGER binding energy, electrons are CLOSER to the nucleus
Molecular formula for a compound is… (in relation to empirical)
… a whole number multiple of the empirical formula ratio
Coulomb’s Law:
The attractive force between an atom’s protons and electrons is directly proportional to the number of protons (effective charge = Zeff) and indirectly proportional to the square of the distance between the nucleus and the electrons
When an electron is in a higher energy level, it is ____ away from the nucleus, therefore has ____ coulombic attraction to the nucleus and is therefore easier to remove (lower 1st ionization energy)
It is FARTHER away, has LESS coulombic attraction
Moving across a row on the periodic table, the Zeff _______, therefore the valence electrons are more attracted to the nucleus, therefore the atomic radius _______ and the ionization energy ________
the Zeff INCREASES, therefore the atomic radius DECREASES and the ionization energy INCREASES
Elements in the same group have _____ chemical and physical properties
SIMILAR chemical and physical properties
On the periodic table metals are on the ____ side of the zig-zag line and the nonmetals are on the ___ side of this line
Metals = Left
Nonmetals = right
Cations (+) are _______ than their atoms since you are ______ valence electrons that are farther from the nucleus
SMALLER than their atoms, REMOVING valence electrons
Anions (-) are ____ than their atoms since ______ eletrons increases electron-electron repulsions without increasing nuclear charge
LARGER than their atoms since ADDING electrons increases…