1: Temperature and Heat Transfer Flashcards
What is temperature?
Macroscopic: Temperature is a measure of the degree of hotness of an object.
Microscopic: Temperature is a measure of the average kinetic energy per molecule in a body
Which properties of substances allow us to indicate temperature?
thermometric properties: temperature-dependent, physical properties. some examples include colour, volume etc.
What are two features of reference points to define a temperature scale?
They are fixed and easily reproducible.
What are the fixed points for the celcius temperature scale?
lower fixed point: ice point (the temperature of melting ice under normal atmospheric pressure)
upper fixed point: steam point (the temperature of steam above boiling water under normal atmospheric pressure)
How is the range between the fixed points divided in the celcius temperature scale?
It is divided into 100 equal divisions with each division being called 1°C.
Express a temperature T (ºC) in Fahrenheit and Kelvin.
T (ºF) = 9/5 T(ºC) + 32
T (K) = (ºC) + 273
How does a liquid-in-glass thermometer work?
The liquid inside expand and contract uniformly when temperature changes. The level of liquid risen up from its bulb indicates the temperature measured by the thermometer.
What is meant by calibrating an unmarked thermometer?
Marking a scale on a thermometer
How do you calibrate a thermometer by using a practical method?
- Put the thermometer into a beaker of melting ice (0°C) and mark the liquid level.
- Put the thermometer into a beaker of boiling water (100°C) and mark the liquid level.
- Divide the length between the two marked points to 10 portions. Each portion stands for 10°C.
How do you calibrate a thermometer by a graphical method?
- Measure the liquid level when the thermometer is put in melting ice and boiling water.
- Draw a graph of length of liquid against the temperature.
- Read from the graph or calculate the calibration from a uniform proportion.
(S4 Test 1) A faulty mercury-in-glass thermometer reads 1.2C at ice point and 99.6C at steam point. What is the actual temperature when the faulty thermometer reads 25C?
Assumption: the length of the liquid column varies linearly with temperature, because mercury’s volume varies linearly with temperature.
Approach: using proportion, uniform ratio, or equation of straight line
(99.6-1.2)/100 = 0.984: for every 1ºC increase shown on the faulty thermometer, the real temperature increase is 0.984ºC.
Starting from 0ºC, where the faulty thermometer reads 1.2ºC, the faulty reading is increased by (25-1.2)ºC. The real temperature increases by (23.8/0.984)ºC, which means the real temperature is 24.2ºC.
What affects the accuracy of a thermometer?
- The length of the liquid column should vary linearly with temperature for a thermometer to be accurate.
The accuracy is guaranteed by uniform cross-sectional area of the capillary tube, and the uniform expansion of the liquid per unit temperature.
What is sensitivity and how can a thermometer become more sensitive?
Sensitivity refers to the ability to record a small change in temperature. For liquid-in-glass thermometer, sensitivity can be increased by using a narrower tube (more variation in column length), increasing the amount of liquid, and using a liquid that expands more when heated.
Can an accurate thermometer be less sensitive, and can a sensitive thermometer be inaccurate?
Yes: an accurate thermometer is less sensitive if the capillary tube is thicker, or there is less liquid.
Yes: a sensitive thermometer can have an inaccurate scale after marking the scale randomly.
What is response time and how can it be shortened?
Response time is the time needed for the reading of the thermometer to become stable. It can be faster if the thermometer has thin walls, or if highly conducing liquid is used.
What are two advantages and a disadvantage of using a mercury thermometer?
advantages: can measure high temperatures up to 357°C, has a quick response to temperature changes
disadvantage: mercury is poisonous.
Give two reasons why water is not used in thermometers.
- It has a non-uniform expansion, in which it contracts when heated from 0ºC to 4ºC, but expands when heated to 4ºC or beyond.
- It has a high specific heat capacity, meaning that it has to absorb a large amount of energy with only a small change in temperature.
What are two advantages and a disadvantage of using an alcohol thermometer?
advantages: can measure low temperatures down to -115°C, is not poisonous
disadvantage: slow response to temperature changes.
How does a rotary thermometer with copper and iron bimetallic strip work? (given: the copper strip is put on the outside)
When heated, copper expands more than iron, which makes the strip in the thermometer bend, displaying different temperatures.
What are the properties, molecular arrangement, and molecular movement in a solid?
properties: fixed volume and shape
arrangement: closely packed fixed in positions
movement: vibrate about a fixed position
What are the properties, molecular arrangement, and molecular movement in a liquid?
properties: fixed volume but unfixed shape
arrangement: closely packed but not fixed in positions
movement: move freely